Biaryl thioether synthesis via CuI catalyzed dominothiolation of aryl halides in the presence of DMAP as ligand

被引：36

作者：

Roy, Subhasish ^{[1
]}

Phukan, Prodeep ^{[1
]}

机构：

[1] Gauhati Univ, Dept Chem, Gauhati 781014, Assam, India

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 19期

关键词：

DMAP; CuI; C-S coupling; Aryl halide; Thiourea; CROSS-COUPLING REACTIONS; BARBIER-TYPE ALLYLATION; EFFICIENT LIGAND; N-ARYLATION; C-N; NUCLEOPHILIC-SUBSTITUTION; HIGHLY EFFICIENT; S BOND; COPPER; THIOLS;

D O I：

10.1016/j.tetlet.2015.03.075

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An improved protocol has been developed for the synthesis of symmetrical biaryl sulfides via a dominothiolation reaction using CuI as catalyst in the presence of DMAP as ligand. The coupling reaction of aryl halides was carried out in the presence of 5 mol % of CuI and 20 mol % of DMAP using thiourea as sulfur transfer agent. High yields of corresponding product were obtained by carrying out the reaction in DMSO at 120 degrees C. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：2426 / 2429

页数：4

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