Luminescent mixed-ligand iodido copper(I) coordination polymers having antenna effect

被引：10

作者：

Sugimoto, Satoshi ^{[1
]}

Ohtsu, Hideki ^{[1
]}

Tsuge, Kiyoshi ^{[1
]}

机构：

[1] Univ Toyama, Grad Sch Sci & Engn, Toyama, Toyama 9308555, Japan

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2018年 / 353卷

关键词：

Copper(I) coordination polymer; Mixed-ligand; Solid solution; Antenna effect; METAL-ORGANIC FRAMEWORKS; THERMOCHROMIC-LUMINESCENCE; COMPLEXES; TRANSITION; CLUSTERS; EMITTERS; YELLOW; HALIDE; BLUE; RED;

D O I：

10.1016/j.jphotochem.2017.08.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Luminescent iodido copper(l) coordination polymers [Cu2I2(PPh3)(2)(mu-bpa)(n) and [Cu2I2(PPh3)(2)(mu-bpe)](n) were synthesized and their luminescent properties were clarified (bpa: bis(4-pyridyl)ethane, bpe: transbis(4-pyridyl)ethylene). By taking advantage of their isomorphous relation, mixed-ligand luminescent coordination polymers [Cu2I2(PPh3)(2)(bPa)((1-x))(bPe)(x)](n) were prepared as solid solutions with various ratio of bpa:bpe. The measurements of their photophysical properties revealed that the mixed-ligand complexes are antenna materials where the bpa and bpe sites serve as the donor and the acceptor sites, respectively. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：602 / 611

页数：10

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