A versatile method for the conversion of aldoximes to nitriles using silica gel/thionyl chloride

被引：6
|
作者：
Kazemi, F [1 ]
Kiasat, AR [1 ]
Fadavipoor, E [1 ]
机构：
[1] Chamran Univ, Coll Sci, Chem Dept, Ahvaz, Iran
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2004年 / 179卷 / 02期
关键词：
aldoxime; nitrile; silica gel; thionyl chloride;
D O I：
10.1080/10426500490262586
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A simple convenient procedure for dehydration of aldoximes has been developed using silica gel/thionyl chloride in heterogeneous conditions. The method has been found to be effective for a wide range of aromatic oximes.
引用
下载
收藏
页码：433 / 436
页数：4
相关论文
共 50 条
  • [41] Determination of molybdenum(VI) in aqueous solution using trioctylmethylammonium chloride loaded silica gel
    Sato, K
    Suzuki, M
    Hilman, K
    Goto, T
    BUNSEKI KAGAKU, 1996, 45 (02) : 175 - 179
  • [42] Synthesis of TS-1 nanocrystals on silica gel via steam-assisted dry gel conversion method
    Ke, Xue-Bin
    Xu, Li
    Zeng, Chang-Feng
    Zhang, Li-Xiong
    Xu, Nan-Ping
    Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities, 2007, 28 (08): : 1411 - 1415
  • [43] Synthesis of TS-1 nanocrystals on silica gel via steam-assisted dry gel conversion method
    Ke, Xue-Bin
    Xu, Li
    Zeng, Chang-Feng
    Zhang, Li-Xiong
    Xu, Nan-Ping
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2007, 28 (08): : 1411 - 1415
  • [44] Chemoselective protection of carbonyl compounds as dithioacetals using silica gel supported aluminium chloride
    Tamami, B
    Borujeny, KP
    SYNTHETIC COMMUNICATIONS, 2003, 33 (24) : 4253 - 4258
  • [45] A clean conversion of carbonyl compounds to oximes using silica gel supported hydroxylamine hydrochloride
    Kiasat, AR
    Kazemi, F
    Nourbakhsh, K
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2004, 179 (06) : 1193 - 1196
  • [46] A convenient method for the preparation of nitriles and carbodiimides using N-methyl-2-pyridinecarbamoyl chloride
    Lee, JI
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1995, 16 (12) : 1143 - 1145
  • [47] Environmentally compliant silica conversion coatings prepared by sol-gel method for aluminum alloys
    Hamdy, Abdel Salam
    Butt, D. P.
    SURFACE & COATINGS TECHNOLOGY, 2006, 201 (1-2): : 401 - 407
  • [48] AN ALTERNATIVE METHOD TO PREPARE NITRILE OXIDES FROM PRIMARY NITRO-COMPOUNDS BY USING THIONYL CHLORIDE AND TRIETHYLAMINE
    CHEN, YJ
    LI, CN
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1993, 40 (02) : 203 - 207
  • [49] New preparation method of poly(amide-imide)s using direct polycondensation with thionyl chloride and their characterization
    Hong, YT
    Jin, MY
    Suh, DH
    Lee, JH
    Choi, KY
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1997, 248 : 105 - 122
  • [50] A mild and efficient method for the conversion of aldehydes into nitriles and thiols into disulfides using an ionic liquid oxidant
    Hosseinzadeh, Rahman
    Golchoubian, Hamid
    Nouzarian, Mahboobe
    RESEARCH ON CHEMICAL INTERMEDIATES, 2015, 41 (07) : 4713 - 4725
12345