The kinetics of transformation of isopentenols in the presence of the Nafion-H catalyst

被引:0
|
作者
Ryabova, RS [1 ]
Osipova, GF [1 ]
Librovich, NB [1 ]
机构
[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 117977, Russia
关键词
kinetics; catalysis; solid acids; acidity;
D O I
10.1007/BF02494529
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The kinetics of transformation of 3-methyl-1-buten-3-ol in the presence of the Nafion-H catalyst was studied. A comparison between the data obtained and those for the reaction catalyzed by sulfuric acid showed that under the same conditions, the macroscopic acidic properties of Nafion-H correspond to the catalytic activity of 8-15% sulfuric acid.
引用
收藏
页码:2034 / 2036
页数:3
相关论文
共 50 条
  • [21] Nafion-H catalysed isomerization of epoxides to aldehydes and ketones
    Prakash, GKS
    Mathew, T
    Krishnaraj, S
    Marinez, ER
    Olah, GA
    APPLIED CATALYSIS A-GENERAL, 1999, 181 (02) : 283 - 288
  • [22] Direct benzoylation with benzoic acids using Nafion-H, a solid perfluoroalkanesulfonic acid as an efficient catalyst.
    Olah, GA
    Mathew, T
    Prakash, GKS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : B240 - B240
  • [23] PERFLUORINATED RESINSULFONIC ACID (NAFION-H) CATALYSIS IN SYNTHESIS
    OLAH, GA
    IYER, PS
    PRAKASH, GKS
    SYNTHESIS-STUTTGART, 1986, (07): : 513 - 531
  • [24] Nafion-H catalysed isomerization of epoxides to aldehydes and ketones
    Donald P. Katherine B. Loker H., Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, United States
    Appl Catal A Gen, 2 (283-288):
  • [25] NAFION-H AS CATALYST FOR ISOBUTANE/2-BUTENE ALKYLATION COMPARED WITH A CERIUM EXCHANGED Y-ZEOLITE
    RORVIK, T
    DAHL, IM
    MOSTAD, HB
    ELLESTAD, OH
    CATALYSIS LETTERS, 1995, 33 (1-2) : 127 - 134
  • [26] Synthesis of fluorinated benzaldimines from benzylamines using nafion-H, a solid perfluorinated resinsulfonic acid, as catalyst.
    Prakash, GKS
    Panja, C
    Torok, B
    Battamack, P
    Mathew, T
    Olah, GA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U646 - U646
  • [27] Perfluorinated resinsulfonic acid (nafion-H) catalysis in organic synthesis
    Yamato, Takehiko
    Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 1995, 53 (06): : 487 - 499
  • [28] Nafion-H catalyzed cyclocondensation reaction for the synthesis of octahydroquinazolinone derivatives
    Lin, Haixia
    Zhao, Qingjie
    Xu, Bin
    Wang, Xiaohong
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 268 (1-2) : 221 - 226
  • [29] The use of Nafion-H® as an efficient catalyst for the deprotection of trimethylsilyl ethers to their corresponding alcohols under mild and heterogeneous conditions
    Zolfigol, MA
    Mohammadpoor-Baltork, I
    Habibi, D
    Mirjalili, BF
    Bamoniri, A
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2004, 179 (11) : 2189 - 2193
  • [30] STRUCTURE AND CHEMISTRY OF NAFION-H - A FLUORINATED SULFONIC-ACID POLYMER
    SONDHEIMER, SJ
    BUNCE, NJ
    FYFE, CA
    JOURNAL OF MACROMOLECULAR SCIENCE-REVIEWS IN MACROMOLECULAR CHEMISTRY AND PHYSICS, 1986, C26 (03): : 353 - 413