Upgrading Traditional Pulp Mill into Biorefinery Platform: Wheat Straw as a Feedstock

被引:14
|
作者
Jiang, Jun-Gang [1 ]
Yuan, Tong-Qi [1 ]
Wang, Shuang-Fei [2 ]
Liu, Shi-Jie [3 ]
Shi, Xiao-Dan [4 ]
Zheng, Lu [4 ]
Sun, Run-Cang [1 ]
机构
[1] Beijing Forestry Univ, Beijing Key Lab Lignocellulos Chem, 35 Tsinghua East Rd, Beijing 100083, Peoples R China
[2] Guangxi Univ, Light Ind & Food Engn Coll, 100 Daxue East Rd, Nanning 530004, Peoples R China
[3] South China Univ Technol, Sch Light Ind & Engn, 381 Wushan Rd, Guangzhou 510641, Guangdong, Peoples R China
[4] Shanghai Dongsheng New Mat Co Ltd, 388 Tianlin Rd, Shanghai 200233, Peoples R China
来源
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 11期
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
Wheat straw; Dilute acid pretreatment; Soda-AQ delignification; Xylose; Cellulose fiber; Lignin; LIGNIN-CARBOHYDRATE COMPLEXES; DILUTE-ACID PRETREATMENT; ENZYMATIC-HYDROLYSIS; RICE STRAW; STRUCTURAL-CHARACTERIZATION; STEAM-EXPLOSION; SULFURIC-ACID; FRACTIONATION; HEMICELLULOSE; WATER;
D O I
10.1021/acssuschemeng.8b03743
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To maximize utilization of lignocellulose, a two-stage process based on dilute acid pretreatment followed by soda-AQ post-treatment was adopted for wheat straw fractionation. The three main components of wheat straw were successfully separated and recovered, and 15.2% degraded sugars and 35.0% cellulose fibers were obtained under the optimum condition using the dilute acid pretreatment with 0.6% H2SO4 at 130 degrees C for 60 min. This was followed by 16% NaOH and 0.05% AQ at 140 degrees C for 60 min. The cellulose fiber presented a high purity (91.0%) with a crystallinity of 64.7%, and its average degree of polymerization was 997. Meanwhile, the lignin (18.4%) obtained from the new pattern of the straw pulping process showed an extremely low sugar content (0.73%) which exhibited a promising potential for further applications. Under the proposed biorefinery platform, over 80% of the three major components were recovered from straw (82.1%). These results highlight the maximum utilization of lignocellulosic biomass based on the integrated biorefinery platform, which provides a promising future to upgrade traditional pulp mill performance.
引用
收藏
页码:15284 / 15291
页数:15
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