Transition-Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts

被引：46
|
作者：
Yu, Hao [1 ]
Li, Zhen [1 ]
Bolm, Carsten [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany
来源：
ORGANIC LETTERS | 2018年 / 20卷 / 22期
关键词：
PALLADIUM-CATALYZED ARYLATION; HYPERVALENT IODINE REAGENTS; BOND-FORMING REACTIONS; ARYL SULFOXIDES; ENANTIOSELECTIVE ARYLATION; ARYLBORONIC ACIDS; ALLYL SULFOXIDES; ANIONS; ALKYLATION; LIGANDS;
D O I：
10.1021/acs.orglett.8b03046
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A transition-metal-free arylation of sulfenate anions generated from beta-sulfinyl esters with diaryliodonium salts was developed. In this process, a new C-S bond is formed under mild reaction conditions providing a wide range of S,S-diaryl and S-alkyl S-aryl sulfoxides.
引用
收藏
页码：7104 / 7106
页数：3
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