Synthesis of the giant dielectric constant material CaCu3Ti4O12 by wet-chemistry methods

被引:96
|
作者
Liu, Jianjun [1 ]
Smith, Robert W.
Mei, Wai-Ning
机构
[1] Univ Nebraska, Dept Phys, Omaha, NE 68182 USA
[2] Univ Nebraska, Dept Chem, Omaha, NE 68182 USA
关键词
D O I
10.1021/cm0716553
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CaCu(3)Ti(4)O(12) (CCTO) has a giant dielectric constant of up to 10(5) at room temperature and great potential for technological application. In this work, we report two wet-chemistry methods to synthesize CCTO at relatively low temperatures and short reaction times. The pure-phase sample was obtained at 800 degrees C for 0.5 h, and the grain size of a pellet sample sintered at 1030 degrees C has a homogeneous distribution in the range of 0.4-1.5 mu m.
引用
收藏
页码:6020 / 6024
页数:5
相关论文
共 50 条
  • [21] Dielectric relaxations and formation mechanism of giant dielectric constant step in CaCu3Ti4O12 ceramics
    Ni, Lei
    Chen, Xiang Ming
    APPLIED PHYSICS LETTERS, 2007, 91 (12)
  • [22] Structural model of planar defects in CaCu3Ti4O12 exhibiting a giant dielectric constant
    Whangbo, MH
    Subramanian, MA
    CHEMISTRY OF MATERIALS, 2006, 18 (14) : 3257 - 3260
  • [23] Synthesis and preparation of high dielectric constant CaCu3Ti4O12 ceramic powder
    State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
    Rengong Jingti Xuebao, 2007, 3 (589-591):
  • [24] Origin of Giant Dielectric Permittivity in CaCu3Ti4O12 Ceramics
    Hao Wen-Tao
    Zhang Jia-Liang
    Tan Yong-Qiang
    Zheng Peng
    Wang Chun-Lei
    JOURNAL OF INORGANIC MATERIALS, 2011, 26 (10) : 1058 - 1062
  • [25] Origin of the temperature stability of dielectric constant in CaCu3Ti4O12
    Luo, X. J.
    Zhang, Y. T.
    Xu, D. H.
    Chen, S. S.
    Wang, Y.
    Chai, Y.
    Liu, Y. S.
    Tang, S. L.
    Yang, C. P.
    Baerner, K.
    CERAMICS INTERNATIONAL, 2019, 45 (10) : 12994 - 13003
  • [26] The effect of processing on the giant dielectric properties of CaCu3Ti4O12
    Bender, BA
    Pan, MJ
    MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 117 (03): : 339 - 347
  • [27] Mechanochemical Processing of CaCu3Ti4O12 with Giant Dielectric Properties
    Espinoza-Gonzalez, Rodrigo
    Vega, Evelyn
    Tamayo, Rocio
    Criado, Jose M.
    Jesus Dianez, M.
    MATERIALS AND MANUFACTURING PROCESSES, 2014, 29 (10) : 1179 - 1183
  • [28] High dielectric constant in CaCu3Ti4O12 multiphased ceramics
    Lebey, T
    Guillemet, S
    Bley, V
    Boulos, M
    Durand, B
    Proceedings of the 2005 International Symposium on Electrical Insulating Materials, Vols, 1-3, 2005, : 784 - 787
  • [29] Physical aspects of colossal dielectric constant material CaCu3Ti4O12 thin films
    Deng, Guochu
    He, Zhangbin
    Muralt, Paul
    JOURNAL OF APPLIED PHYSICS, 2009, 105 (08)
  • [30] Decrease of dielectric loss in giant dielectric constant CaCu3Ti4O12 ceramics by adding CaTiO3
    Yan, Yueyue
    Jin, Lei
    Feng, Lixin
    Cao, Guanghan
    MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2006, 130 (1-3): : 146 - 150