Formal total synthesis of (±)-hirsutic acid C using the tandem Rh(I)-catalyzed [(5+2)+1] cycloaddition/aldol reaction

被引：37
|
作者：
Yuan, Changxia [1 ]
Jiao, Lei [1 ]
Yu, Zhi-Xiang [1 ]
机构：
[1] Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Beijing 100871, Peoples R China
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 43期
关键词：
STEREOCONTROLLED TOTAL-SYNTHESIS; SIGMATROPIC 1,2-ACYL SHIFT; ENE-VINYLCYCLOPROPANES; (+)-HIRSUTIC ACID; METATHESIS; EFFICIENT;
D O I：
10.1016/j.tetlet.2010.08.028
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A concise formal total synthesis of the linear triquinane natural product (+/-)-hirsutic acid C has been achieved. This synthesis features a tandem Rh(I)-catalyzed [(5+2)+1] cycloaddition/aldol reaction as the key step to build the triquinane skeleton. (C) 2010 Elsevier Ltd. All rights reserved.
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页码：5674 / 5676
页数：3
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