Recognition and Sensing of Chiral Organic Molecules by Chiral Porphyrinoids: A Review

被引：15

作者：

Travagliante, Gabriele ^{[1
]}

Gaeta, Massimiliano ^{[1
]}

Purrello, Roberto ^{[1
]}

D'Urso, Alessandro ^{[1
]}

机构：

[1] Univ Catania, Dipartimento Sci Chim, Viale Andrea Doria 6, I-95125 Catania, Italy

来源：

CHEMOSENSORS | 2021年 / 9卷 / 08期

关键词：

chirality; chiral recognition; sensing; porphyrin; chiral guest; circular dichroism; ABSOLUTE CONFIGURATIONAL ASSIGNMENTS; AMINO-ACID ESTERS; ENANTIOSELECTIVE RECOGNITION; SUPRAMOLECULAR CHIROGENESIS; BICONCAVE PORPHYRIN; CIRCULAR-DICHROISM; GUEST STRUCTURE; BIS-CHLORIN; HOST; DISCRIMINATION;

D O I：

10.3390/chemosensors9080204

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Porphyrinoids are extremely attractive for their electronic, optical, and coordination properties as well as for their versatile substitution at meso/beta-positions. All these features allow porphyrinoids to behave as chiroptical hosts for chiral recognition by means of non-covalent interactions towards chiral guests. Over the years, chiral discrimination of chiral molecules such as amino acids, alcohols, amines, hydroxy-carboxylic acids, etc. has aroused the interest of the scientific community. Hence, this review aims to report on the progress to date by illustrating some relevant research regarding the chiral recognition of a multitude of chiral organic guests through several chiral mono- and bis-porphyrins via different spectroscopic techniques.

引用

页数：22

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