A trimetallic compound containing Zn-Zr bonds:: Cp2Zr(ZnR)2 (Cp = C5H5; r = C6H3-2,6-(2,4,6-i-Pr3C6H2)2)

被引：25

作者：

Wang, Yuzhong

Quillian, Brandon

Wannere, Chaitanya S.

Wei, Pingrong

Schleyer, Paul v. ^{[1
]}

Robinson, Gregory H.

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

[2] Univ Georgia, Ctr Computat Chem, Athens, GA 30602 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 12期

关键词：

D O I：

10.1021/om700319k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

m-Terphenylzinc iodides RZnI2Li(OEt2)(2) (1) and RZnI (2) (R = C6H3-2,6-(2,4,6-i-Pr3C6H2)(2)) were prepared and structurally characterized. The sodium metal reduction of Cp2ZrCl2 with 2 afforded Cp2Zr(ZnR)(2) (3) as the first structurally characterized compound containing a Zn-Zr bond. The nature of the unique Zn-Zr bond for 3 was further probed by DFT computations.

引用

页码：3054 / 3056

页数：3

共 50 条

[21] H-1 AND C-13 NMR EVIDENCE FOR THE INTERMEDIATE SPECIES [(CPZRCL)(MU-ETA-1-ETA-5-C5H4)]2 - CYCLOPENTADIENYL C-H BOND ACTIVATION BY THERMOLYSIS OF [CP2ZR(H)CL]N, CP2ZR(R)CL, AND [CP2ZRCL]2
CHOUKROUN, R
RAOULT, Y
GERVAIS, D
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 391 (02) : 189 - 194
[22] NatureoftheGa-GabondinginNa2[Arx*GaGaArx*](Arx*=C6H3-2,6-（C6H5）2):Electronlocalizationfunctionanalysis
SUN JieMENG LingPengZHENG ShiJunSUN Zheng LI XiaoYan College of Chemistry and Material ScienceHebei Normal UniversityShijiazhuang China
Science China(Chemistry), 2012, 55 (07) : 1387 - 1394
[23] Ga-Ga multiple bond in Na2[Ar*GaGaAr*] (Ar* = C6H3-2,6-(C6H2-2,4,6-i-Pr3)2)
Takagi, N
Schmidt, MW
Nagase, S
ORGANOMETALLICS, 2001, 20 (08) : 1646 - 1651
[24] P-H functionalised phosphinoalkoxides as ligands:: synthesis and catalytic properties of [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp)-C6H10)] (Tipp=2,4,6-Pr3iC6H2), [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)5}-C6H10)] and [Cp2Zr(BH4)(cyclo-1-O-2-PH(Mes)(BH3)-C6H10)] (Mes=2,4,6-Me3C6H2), and molecular structure of (RC,RC,RP/SC,SC,SP)-[Cp2Zr(Me(cyclo-1-O-2-PH(Tipp)- C6H10)]
Koch, T
Blaurock, S
Hey-Hawkins, E
Galan-Fereres, M
Plat, D
Eisen, MS
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 595 (01) : 126 - 133
[25] Effect of solvent on reactions of CP2Zr{(μ-H)2BHR}2 and CP2ZrH{(μ-H)2BHR} (R = CH3, Ph) with B(C6F5)3
Liu, Fu-Chen
Chen, Shou-Chon
Lee, Gene-Hsian
Peng, Shie-Ming
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (12) : 2375 - 2384
[26] Synthesis and characterization of the monomeric terphenyl metal halides Ge(Cl){C6H3-2,6-Trip2} (Trip = C6H2-2,4,6-i-Pr3) and Sn(I){C6H3-2,6-Trip2} and the terphenyl metal amide Sn{N(SiMe3)2}{C6H3-2,6-Trip2}
Pu, LH
Olmstead, MM
Power, PP
Schiemenz, B
ORGANOMETALLICS, 1998, 17 (26) : 5602 - 5606
[27] The Reactions of Aryl Tin(II) Hydrides {AriPr6Sn(μ-H)}2 (AriPr6 = C6H3-2,6-(C6H2-2,4,6-iPr3)2) and {AriPr4Sn(μ-H)}2 (AriPr4 = C6H3-2,6(C6H3-2,6-iPr2)2) with Aryl Alkynes: Substituent Dependent Structural Isomers
McCrea-Hendrick, Madison L.
Wang, Shuai
Gullett, Kelly L.
Fettinger, James C.
Power, Philip P.
ORGANOMETALLICS, 2017, 36 (19) : 3799 - 3805
[28] Novel Neutral Zirconaborane [(Cp2Zr)2B5H11]: An arachno-B3H9 Analogue (Cp = η5-C5H5)
Roy, Dipak Kumar
Mondal, Bijan
De, Anangsha
Panda, Subhankar
Ghosh, Sundargopal
ORGANOMETALLICS, 2015, 34 (05) : 908 - 912
[29] Five-coordinate carbon center and Zr to H, B, and C bonding in Cp2Zr[CH2-(BH{C6F5}2)2]
Radius, Udo
Silverio, Sandro Johannes
Hoffmann, Roald
Gleiter, Rolf
Organometallics, 1996, 15 (17):
[30] THE ELECTRONIC-STRUCTURES OF [(C5H4-C6H5)CR(CO)3]-, [(C6H4COC6H5)CR(CO)3)-, [(C5H4CH2C6H5)CR(CO)3]-, [(C5H4C2H2C6H5)CR(CO)3]- AND (C6H5-C5H4)MN(CO)3, (C6H5COC5H4)MN(CO)3, (C6H5CH2C5H4)MN(CO)3, (C6H5C2H2C5H4)MN(CO)3
FITZPATRICK, NJ
GOGAN, NJ
SAYAL, PK
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 301 (02) : C31 - C34

← 1 2 3 4 5 →