Potential levels of metal complexes of 8-hydroxyquinoline

被引：5

作者：

Nishikiori, Hiromasa ^{[1
]}

Nakamura, Shogo ^{[1
]}

Natori, Daichi ^{[1
]}

Teshima, Katsuya ^{[1
]}

机构：

[1] Shinshu Univ, Fac Engn, Dept Environm Sci & Technol, 4-17-1 Wakasato, Nagano 3808553, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2016年 / 662卷

关键词：

8-Hydroxyquinoline; Titanium; Zinc; Titania; Surface complex; Photoinduced electron transfer; SURFACE COMPLEXES; ORGANIC-LIGANDS; TIO2; ELECTRON; TITANIA; RECOMBINATION; NANOPARTICLES; CONVERSION; EMISSION; STATES;

D O I：

10.1016/j.cplett.2016.07.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The potential levels of 8-hydroxyquinoline and its titanium and zinc complexes were determined by electrochemical measurements and quantum chemical calculations. The HOMO and LUMO levels of the complexes were lower and higher than those of the iodine redox couple and titania conduction band edge, respectively. This indicated that the electrons can be transferred from the electrolyte to the titania via the complexes. The 8-hydroxyquinoline formed titanium complexes on the titania surface and formed zinc complexes in the presence of zinc ions on the surface. It is suggested that electrons were injected from the complex LUMO into the titania conduction band. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：146 / 151

页数：6

共 50 条

[21] SCANDIUM(III) COMPLEXES OF 8-HYDROXYQUINOLINE AND DERIVATIVES
CORSINI, A
TONEGUZZ.F
THOMPSON, M
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1973, 51 (08): : 1248 - 1256
[22] Polydentate Analogues of 8-Hydroxyquinoline and Their Complexes with Ruthenium
El Ojaimi, Maya
Thummel, Randolph P.
[J]. INORGANIC CHEMISTRY, 2011, 50 (21) : 10966 - 10973
[23] THE CHEMISTRY OF SOME 8-HYDROXYQUINOLINE COMPLEXES OF VANADIUM
BLAIR, AJ
PANTONY, DA
MINKOFF, GJ
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1958, 5 (04): : 316 - 331
[24] IR SPECTRA OF LANTHANIDE 8-HYDROXYQUINOLINE COMPLEXES
ALY, HF
ABDELKER.FM
KANDIL, AT
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1971, 33 (12): : 4340 - &
[25] EXTRACTION OF CATIONIC COMPLEXES OF ZINC WITH 8-HYDROXYQUINOLINE
RAKOVSKII, EE
SEREBRYANYI, BL
KLYUEVA, ND
[J]. JOURNAL OF ANALYTICAL CHEMISTRY OF THE USSR, 1974, 29 (06): : 927 - 933
[26] URANIUM(6) COMPLEXES OF 8-HYDROXYQUINOLINE AND DERIVATIVES
CORSINI, A
ABRAHAM, J
THOMPSON, M
[J]. CHEMICAL COMMUNICATIONS, 1967, (21) : 1101 - &
[27] Synthesis and characterization of 5-substituted 8-hydroxyquinoline derivatives and their metal complexes
Li, Lihua
Xu, Bing
[J]. TETRAHEDRON, 2008, 64 (49) : 10986 - 10995
[28] Synthesis and Photoluminescence Properties of 8-Hydroxyquinoline Schiff Base Derivatives and Their Metal Complexes
Wang, Hui
Zhang, Yonghong
Tao, Jingqi
Zeng, Zhuo
Zeng, Heping
[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2012, 32 (02) : 354 - 359
[29] 8-hydroxyquinoline based multipodal systems: Effect of spatial placement of 8-hydroxyquinoline on metal ion recognition
Singh, Prabhpreet
Kumar, Subodh
[J]. JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2007, 58 (1-2) : 89 - 94
[30] FACTORS INFLUENCING THE FUNGISTATIC ACTION OF 8-HYDROXYQUINOLINE (OXINE) AND ITS METAL COMPLEXES
ANDERSON, BI
SWABY, RJ
[J]. AUSTRALIAN JOURNAL OF SCIENTIFIC RESEARCH SERIES B-BIOLOGICAL SCIENCES, 1951, 4 (03): : 275 - 282

← 1 2 3 4 5 →