Wavevector dependent dielectric constant of the MCY water model

被引：4

作者：

Omelyan, IP

机构：

[1] Inst. for Condensed Matter Physics, Natl. Ukrainian Academy of Sciences, UA-290011 Lviv

来源：

PHYSICS LETTERS A | 1996年 / 220卷 / 1-3期

关键词：

dielectric constant; models of water; Monte Carlo simulations;

D O I：

10.1016/0375-9601(96)00526-9

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The wavevector-dependent dielectric constant for a MCY model of water is evaluated in a wide region of wavenumbers by Monte Carlo simulations using the reaction field geometry. It is shown that values for the longitudinal component of the dielectric constant, calculated within the exact site-site description, differ in a characteristic way from those obtained by the point dipole approximation which is usually used in computer experiment. The intramolecular shape of the dielectric constant and the Kirkwood factor is examined in the infinite wavevector limit.

引用

页码：167 / 177

页数：11

共 50 条

[21] ON THE ORIENTATIONAL STRUCTURE AND DIELECTRIC-PROPERTIES OF WATER - A COMPARISON OF ST2 AND MCY POTENTIAL
STEINHAUSER, O
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1983, 87 (02): : 128 - 142
[22] Note: On the dielectric constant of nanoconfined water
Zhang, Chao
JOURNAL OF CHEMICAL PHYSICS, 2018, 148 (15):
[23] Dielectric constant of water confined in a nanocavity
Senapati, S
Chandra, A
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (22): : 5106 - 5109
[24] PRESSURE COEFFICIENT OF THE DIELECTRIC CONSTANT OF WATER
MAVROIDES, JG
JOURNAL OF CHEMICAL PHYSICS, 1956, 24 (02): : 398 - 399
[25] Wavevector-Dependent Susceptibility in Z-Invariant Pentagrid Ising Model
Helen Au-Yang
Jacques H. H. Perk
Journal of Statistical Physics, 2007, 127 : 221 - 264
[26] Tunable dielectric constant of water at the nanoscale
Renou, R.
Szymczyk, A.
Ghoufi, A.
PHYSICAL REVIEW E, 2015, 91 (03):
[27] ON THE DIELECTRIC CONSTANT OF THE WATER IN WET CLAY
PALMER, LS
PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON SECTION B, 1952, 65 (393): : 674 - 678
[28] DIELECTRIC-CONSTANT OF WATER AND STEAM
SENGERS, JV
MECHANICAL ENGINEERING, 1979, 101 (09) : 44 - 45
[29] THE DIELECTRIC CONSTANT OF WATER AND THE SATURATION EFFECT
BOOTH, F
JOURNAL OF CHEMICAL PHYSICS, 1951, 19 (04): : 391 - 394
[30] The effect of electrolytes on the dielectric constant of water
Lattey, RT
Davies, WG
PHILOSOPHICAL MAGAZINE, 1932, 13 (84): : 444 - 455

← 1 2 3 4 5 →