Raman spectra of titanium Di-, Tri-, and tetra-chlorides

被引:0
|
作者
Miyaoka, H [1 ]
Kuze, T [1 ]
Sano, H [1 ]
Mori, H [1 ]
Mizutani, G [1 ]
Otsuka, N [1 ]
Terano, M [1 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan
来源
PROCEEDINGS OF THE 2000 INTERNATIONAL CONFERENCE ON EXCITONIC PROCESSES IN CONDENSED MATTER | 2001年
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中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We have obtained the Raman spectra of TiCln (n=2, 3, and 4). Assignments of the observed Raman bands were made by a normal mode analysis. The force constants were determined from the observed Raman band frequencies. We have found that the Ti-Cl stretching force constant increases as the oxidation number of the Ti species increases.
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页码:297 / 300
页数:4
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