The thermochromism of the ET(30) betaine in a micro-heterogeneous medium: A spectral and dynamics simulation study

被引：11

作者：

Aliaga, Carolina ^{[1
,2
]}

Briones, Luis ^{[3
]}

Caroli Rezende, Marcos ^{[1
]}

Tirapegui, Cristian ^{[1
]}

机构：

[1] Univ Santiago, Fac Quim & Biol, Santiago, Chile

[2] Univ Santiago, CEDENNA, Ctr Desarrollo Nanociencia & Nanotecnol, Santiago, Chile

[3] Univ Talca, Fac Ingn, Talca, Chile

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2010年 / 349卷 / 02期

关键词：

Thermochromism; Solvatochromism; Micelles; Poloxamers; Pluronics; Molecular dynamics simulation; OXIDE) BLOCK-COPOLYMER; FIELD GRADIENT NMR; FLUORESCENCE SPECTROSCOPY; MOLECULAR-DYNAMICS; AQUEOUS-SOLUTIONS; SOLVENT POLARITY; DYES; SOLVATOCHROMISM; MICELLIZATION; TEMPERATURE;

D O I：

10.1016/j.jcis.2010.05.088

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A spectral investigation of the thermochromic behavior of Reichardt's E-T(30) betaine in aqueous solutions of block copolymers ("poloxamers") P407, P237 and P105 was carried out as a function of temperature and concentration. The betaine microenvironment at various stages of the micellization process in these systems was mimicked with the aid of molecular dynamics simulations of model systems. These consisted of the E-T(30) probe in boxes of water molecules, in the presence of an isolated block copolymer of formula (PEO)(11)-(PPO)(16)-(PEO)(11), and of a micelle formed of 50 of these unimers. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：565 / 570

页数：6

共 50 条

[31] Experimental study and molecular dynamics simulation of wall slip in a micro-extrusion flowing process
Zhao, D.
Jin, Y.
Wang, M.
Song, M.
PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART C-JOURNAL OF MECHANICAL ENGINEERING SCIENCE, 2011, 225 (C5) : 1175 - 1190
[32] Research progress on topological properties and micro-magnetic simulation study in dynamics of magnetic skyrmions
Kong Ling-Yao
ACTA PHYSICA SINICA, 2018, 67 (13)
[33] SIMULATION STUDY AND EXPERIMENTAL TESTING OF FOOT-TERRAIN DYNAMICS IN PIEZOELECTRIC MICRO-ROBOTS
Ryou, Jeong Hoon
Oldham, Kenn
PROCEEDINGS OF THE ASME DYNAMIC SYSTEMS AND CONTROL CONFERENCE 2010, VOL 2, 2010, : 97 - 104
[34] Micro-simulation Study of Vehicular Interactions on Upgrades of Intercity Roads under Heterogeneous Traffic Conditions in India
Arkatkar, Shriniwas S.
Arasan, V. Thamizh
EUROPEAN TRANSPORT-TRASPORTI EUROPEI, 2012, (52):
[35] STUDY OF THE DYNAMICS OF ESTABLISHING THE EQUILIBRIUM TEMPERATURES IN A HETEROGENEOUS Me-C MEDIUM UNDER IMPACT LOADS.
Andreev, V.D.
Voloshin, M.N.
Malik, V.R.
Soviet Journal of Superhard Materials (English translation of Sverkhtverdye Materialy), 1983, 5 (06): : 4 - 8
[36] Influence of strain rate on the compressive behavior of heterogeneous Cu/ Ta multilayer: A molecular dynamics simulation study
Liu, Xuepeng
Xu, Kezhong
Lu, Pin
Wang, Gangfeng
SOLID STATE COMMUNICATIONS, 2024, 379
[37] Heterogeneous growth of calcite at aragonite {001}- and vaterite {001}-melt interfaces: A molecular dynamics simulation study
Nada, Hiroki
Nishimura, Tatsuya
Sakamoto, Takeshi
Kato, Takashi
JOURNAL OF CRYSTAL GROWTH, 2016, 450 : 148 - 159
[38] COUNTERION NMR IN HETEROGENEOUS AQUEOUS SYSTEMS - A MOLECULAR-DYNAMICS SIMULATION STUDY OF THE ELECTRIC-FIELD GRADIENT
LINSE, P
HALLE, B
MOLECULAR PHYSICS, 1989, 67 (03) : 537 - 573
[39] Phase Behavior and Composition Distribution of Multiphase Hydrocarbon Binary Mixtures in Heterogeneous Nanopores: A Molecular Dynamics Simulation Study
de Andrade, Deraldo de Carvalho Jacobina
Nojabaei, Bahareh
NANOMATERIALS, 2021, 11 (09)
[40] Molecular Dynamics Simulation Study on Heterogeneous Structure, Rheology, and Dynamic Correlation of Concentrated Aqueous Solutions of a Lithium Salt
Yamaguchi, Tsuyoshi
JOURNAL OF PHYSICAL CHEMISTRY B, 2025, 129 (03): : 1026 - 1035

← 1 2 3 4 5 →