The Impact of Reducing Carbon on Preparing Li3V2 (PO4)3 via Wet Milling and the Electric Property and Morphology Study of Li3V2 (PO4)3

被引:0
|
作者
Song, Jishun [1 ,2 ]
Cao, Fubiao [1 ,2 ,3 ]
Ma, Xu [1 ,3 ]
Wang, Jinkui [4 ]
Lv, Fei [5 ]
Xu, Ning [5 ]
Cui, Bo [6 ]
机构
[1] Tianjin Univ Technol, Mat Sci & Engn Coll, Tianjin 300384, Peoples R China
[2] TianJin Key Lab Photoelect Display Mat & Device, Tianjin 300384, Peoples R China
[3] Minist Educ, Key Lab Display Mat & Photoelect Devices, Tianjin 300384, Peoples R China
[4] Tianjin Motor Dies Co LTD, Tianjin 300308, Peoples R China
[5] Tanjin B&M Sci & Technol joint Stock Ltd, Tianjin 300384, Peoples R China
[6] Nankai Univ, Tianjin 300071, Peoples R China
来源
关键词
Lithium-ion batteries; Cathode material; Carbon-thermal reduction; Li3V2(PO4)(3); Conductive carbon ECP;
D O I
10.4028/www.scientific.net/AMR.236-238.703
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The cathode material Li3V2 (PO4)(3) is synthesized for Lithium Ion batteries based on wet ball-milling then high temperature carbon-thermal sintering. We had characterized them with the measurements of XRD ray diffraction, elemental analysis and electrochemical property tests. The results show that we synthesized sample is monoclinic structure; We first synthesized the Li3V2 (PO4)(3) through the using conductive carbon, the extra conductive carbon can increase the conductivity of the material. The initial charge capacity is 126.16 mAh/g and initial efficiency is 97.84 % at room temperature, charging voltage3.0 similar to 4.3 V,0.1 C rate charging, respectively and the surface of the material is smooth, it's grains grow better, there are excess conductive carbon even attached to the material to improve the conductivity of the material.
引用
收藏
页码:703 / +
页数:2
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