Regenerated cellulose/graphene nanocomposite films prepared in DMAC/LiCl solution

被引:125
|
作者
Zhang, Xiaomin [1 ]
Liu, Xiaoqing [1 ]
Zheng, Wenge [1 ]
Zhu, Jin [1 ]
机构
[1] Chinese Acad Sci, Ningbo Key Lab Polymer Mat, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China
关键词
Regenerated; Cellulose; Graphene; Nanocomposite; MECHANICAL-PROPERTIES;
D O I
10.1016/j.carbpol.2011.11.054
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Regenerated cellulose/graphene composite films had been prepared by dispersing graphene into cellulose solution in DMAC/LiCl, and then casting the solution onto glass. The thermal stability and mechanical properties of the composite materials, compared with pure regenerated cellulose film, were significantly improved. When the graphene loading was only 0.4 wt.%, the 10% weight loss temperature increased 20 degrees C. The Young's modulus increased from 3.4 to 7.2 GPa, while tensile strength increased from 89 to 148 MPa when 1.6 wt.% graphene was added into cellulose film. The electrical conductivity of the nanocomposite film reached 3.7 x 10(-6) S/cm when 1.6 wt.% graphene was incorporated. The morphology was investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The images revealed that the graphene was nano-dispersed in cellulose matrix. The effect of the graphene content in the nanocomposite material was also investigated. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:26 / 30
页数:5
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