Synthesis and structure of the organoantimony peroxide solvates [Sb4(μ2-O)4(O2)2(C6H3MeO-2,Br-5)8]•1.5C4H8O2 and [Sb4(μ2-O)4(O2)2(C6H3MeO-2,Br-5)8]•6C4H8O2

被引：4
|
作者：
Sharutin, V. V. [1 ]
Sharutina, O. K. [1 ]
Chagarova, O. V. [1 ]
Molokova, O. V. [1 ]
机构：
[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2011年 / 81卷 / 11期
关键词：
Antimony; General Chemistry; Oxime; Peroxy Group; Bridge Oxygen Atom;
D O I：
10.1134/S1070363211110065
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The organoantimony peroxide (Ar2SbO)(4)(O-2)(2) (Ar = C6H3OMe-2, Br-5) was synthesized by the oxidation of Ar3Sb with hydrogen peroxide in the presence or acetoxime or acetophenone oxime in dioxane. The product crystallizes with various content of the solvent molecules in the crystal unit cell [1.5 (I) and 6 (II), respectively]. An X-ray diffraction analysis of the solvates was performed. Four antimony atoms in the peroxide are in the octahedral coordination, and are linked through bridging oxygen atoms and two peroxide groups. The distances Sb-C, Sb-O-bridge, Sb-O-peroxide, O-O and Sb...Sb are 2.117-2.122, 1.960-1.972, 2.193-2.235, 1.461, 1.465 and 3.223-3.237 in I, and 2.112, 2.119, 1.957, 1,966, 2.204, 2,246, 1,467, and 3.2439 in II.
引用
收藏
页码：2246 / 2251
页数：6
相关论文
共 50 条
  • [41] Group 2 metal salts of pyromellitic acid:: [Mg(H2O)6](C10H4O8) and [Ba(C10H4O8)(H2O)5]
    Dale, SH
    Elsegood, MRJ
    Kainth, S
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2003, 59 : M505 - M508
  • [42] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
    Zheng, YQ
    Kong, ZP
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
  • [43] LANTHANIDE OXALATO-SQUARATES - PREPARATION AND CRYSTAL-STRUCTURES OF (CE2 (H2O)8 (C4O4)2 (C2O4)).3H2O AND EU2 (H2O)4 (C4O4)2 (C2O4)
    TROMBE, JC
    PETIT, JF
    GLEIZES, A
    EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY, 1991, 28 (3-4): : 669 - 681
  • [44] Synthesis, Characterization, Thermal Stability and Decomposition Mechanism of [Ru(C12H8N2)3](C4H2O4)(C4H3O4)(C4H4O4)•4H2O
    Shui, Miao
    Shu, Jie
    Li, Rongsheng
    Song, Yue
    Ren, Yuanlong
    Wang, Qingchun
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (11) : 4858 - 4862
  • [45] Synthesis and structural phase transitions of [Mg2Sb2(C4H2O6)2(H2O)8](ClO4)2•5H2O with complex homochiral chains
    Wang, Xiqu
    Makarenko, Tatyana
    Jacobson, Allan J.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2016, 231 (07): : 441 - 448
  • [46] Synthesis and crystal structure of [Fe4O2(H2O)10(C5H5NCOO)4](NO3)8 · 2H2O
    E. A. Mainicheva
    D. G. Samsonenko
    O. A. Gerasko
    V. P. Fedin
    Russian Journal of Coordination Chemistry, 2009, 35 : 908 - 911
  • [47] Synthesis and crystal structure of La(H2O)(C2O4)2•(CN3H6) and of [Nd(H2O)]2(C2O4)4•(NH4)(CN3H6)
    Fourcade-Cavillou, F
    Trombe, JC
    SOLID STATE SCIENCES, 2002, 4 (09) : 1199 - 1208
  • [48] Synthesis and crystal structure of [Fe4O2(H2O)10(C5H5NCOO)4](NO3)8 • 2H2O
    Mainicheva, E. A.
    Samsonenko, D. G.
    Gerasko, O. A.
    Fedin, V. P.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2009, 35 (12) : 908 - 911
  • [49] Speciation and transformation in the synthesis of Cu4(im)4(C4O3H6)2(NO2)4(H2O)4 and [(phen)Cu(C2O4)(H2O)]•H2O
    Gong, Yun
    Li, Hui
    Li, Yang Guang
    Wang, Yong Hui
    Tang, Wang
    Hu, Chang Wen
    JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (01) : 61 - 71
  • [50] THE STRUCTURE OF [VCL3(C4H8O)2(OH)].C4H8O
    BOTTOMLEY, F
    SUTIN, LC
    WHITE, PS
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 : 529 - 531
12345