Fabrication of a high lithium ion conducting lithium borosilicate glass

被引：51
|
作者：
Kim, Chul Eui [1 ]
Hwang, Hyun Chul [1 ]
Yoon, Mi Young [1 ]
Choi, Byung Hyun [2 ]
Hwang, Hae Jin [1 ]
机构：
[1] Inha Univ, Sch Mat Sci & Engn, Inchon, South Korea
[2] Korea Inst Ceram Engn & Technol, Seoul, South Korea
来源：
JOURNAL OF NON-CRYSTALLINE SOLIDS | 2011年 / 357卷 / 15期
关键词：
Li ion conducting glass; Solid electrolyte; Thin film battery; Lithium borosilicate glass; Impedance spectrum; ELECTRICAL-CONDUCTIVITY; ELECTROLYTE; SYSTEM;
D O I：
10.1016/j.jnoncrysol.2011.03.022
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A lithium ion conducting glass, Li(2)O-B(2)O(3)-SiO(2), is fabricated by the conventional melt and quenching technique from a mixture of Li(2)CO(3), B(2)O(3) and SiO(2) powders. It appears that B(2)O(3) decreases the crystallization tendency of the Li(2)O-SiO(2) binary glass, resulting in an expanded glass forming region in the Li(2)O-B(2)O(3)-SiO(2) ternary glass. The maximum conductivity is 2 x 10(-6) S cm(-1) at 25 degrees C for the 50Li(2)O-38B(2)O(3)-12SiO(2) glass sample. The observed high conductivity is due to the mixed former effect. The conductivity strongly depends on the Li(2)O content, but not on K (SiO(2)/B(2)O(3)) in the Li(2)O-B(2)O(3)-SiO(2) ternary glass. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：2863 / 2867
页数：5
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