[1,2-bis(diphenylphosphino)ethane]dichloro(methoxo)oxorhenium(V) dichloromethane solvate

被引:2
|
作者
Beauchamp, AL [1 ]
Sigouin, O [1 ]
机构
[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada
关键词
D O I
10.1107/S1600536805008718
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Re(CH3O)Cl2O(C26H24P2)]center dot CH2Cl2, contains slightly distorted octahedrally coordinated molecules in which the methoxo group is trans to the oxo ligand. A cis arrangement of the Cl atoms is imposed in the equatorial plane by the bidentate diphosphine ligand. The methoxo group is approximately end-on coordinated [Re-O-CH3=168.1 (5)degrees].
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页码:M736 / M737
页数:2
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