White upconversion luminescence in CaF2:Yb3+/Eu3+ powders via the incorporation of Y3+ ions

被引：15
|
作者：
Li, Yangyang [1 ]
Guo, Junjie [1 ]
Liu, Xiaohui [1 ]
Aidilibike, Tuerxun [1 ,2 ]
Qin, Weiping [1 ]
机构：
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Jilin, Peoples R China
[2] Yili Normal Univ, Elect & Informat Engn, Yining 835000, Xinjiang, Peoples R China
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2016年 / 18卷 / 24期
基金：
中国国家自然科学基金;
关键词：
ENERGY-TRANSFER; NANOCRYSTALS; EMISSION; GREEN; BLUE; RED; FLUORESCENCE; ULTRAVIOLET; TM3+;
D O I：
10.1039/c6cp02849g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
White upconversion luminescence (UCL) was achieved under 980 nm excitation in the CaF2:Yb3+/Eu3+ material using Y3+ to adjust the luminescence performance. In this luminescent system, Yb3+ not only plays the role of a sensitizer of Eu3+, but also generates green fluorescence from Yb3+ dimers (2-Yb3+) by cooperative transitions in the CaF2 matrix. One of the primary colors of green corresponds to the 2-Yb3+ cooperative emission exactly. Eu3+ acts as an activator for emitting red and blue fluorescence simultaneously. Interestingly, the color of the UCL can be controlled by adjusting the doping concentration of Y3+ ions, and white UCL was realized when the concentration of Y3+ was 1%.
引用
收藏
页码：16094 / 16097
页数：4
相关论文
共 50 条
  • [31] Innovative approach to tailoring upconversion luminescence in Yb3+/Eu3+ doped CaZrO3 perovskite host matrix
    Khan, Adnan
    Sang, Xu
    Yang, Jiaxin
    Ikram, Muhammad
    Li, Yang
    Rehman, Sadia
    Xu, Rui
    Song, Feng
    Feng, Ming
    CERAMICS INTERNATIONAL, 2024, 50 (21) : 43772 - 43779
  • [32] Luminescence of Eu3+ ions in ultradisperse diamond powders
    Malashkevich, GE
    Lapina, VA
    Semkova, GI
    Pershukevich, PP
    Shevchenko, GP
    JETP LETTERS, 2003, 77 (06) : 291 - 294
  • [33] Luminescence of Eu3+ ions in ultradisperse diamond powders
    G. E. Malashkevich
    V. A. Lapina
    G. I. Semkova
    P. P. Pershukevich
    G. P. Shevchenko
    Journal of Experimental and Theoretical Physics Letters, 2003, 77 : 291 - 294
  • [34] The redistribution of charge density in CaF2:Yb3+
    T. K. Thirumalaisamy
    R. Saravanan
    S. Saravanakumar
    Journal of Materials Science: Materials in Electronics, 2015, 26 : 6683 - 6691
  • [35] Color-tunable upconversion luminescence and prolonged Eu3+ fluorescence lifetime in fluoride KCdF3:Yb3+,Mn2+,Eu3+ via controllable and efficient energy transfer
    Han, Xinxin
    Song, Enhai
    Chen, Weibin
    Zhou, Yayun
    Zhang, Qinyuan
    JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8 (29) : 9836 - 9844
  • [36] Diode-Pumped Yb3+:YLF and Yb3+:CaF2 Laser Performance
    Pirri, Angela
    Alderighi, Daniele
    Toci, Guido
    Nikl, Martin
    Sato, Hiroki
    Tonelli, Mauro
    Vannini, Matteo
    2ND INTERNATIONAL CONFERENCE ON ULTRA-INTENSE LASER INTERACTION SCIENCE, 2010, 1209 : 91 - +
  • [37] Spectroscopy and laser function of CaF2:Yb3+
    Camy, P
    Doualan, JL
    Petit, V
    Renard, S
    Thuau, M
    Moncorgé, R
    JOURNAL DE PHYSIQUE IV, 2004, 119 : 141 - 142
  • [38] The redistribution of charge density in CaF2:Yb3+
    Thirumalaisamy, T. K.
    Saravanan, R.
    Saravanakumar, S.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2015, 26 (09) : 6683 - 6691
  • [39] Sensitized Yb3+ Luminescence of Eu3+/Yb3+-Codoped Fluorosilicate Glass Ceramics
    Luo, Qun
    Qiao, Xvsheng
    Fan, Xianping
    Fu, Hengyi
    Huang, Jinglu
    Zhang, Yijun
    Fan, Bo
    Zhang, Xianghua
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2012, 95 (03) : 1042 - 1047
  • [40] Structural destruction quenching of down- and upconversion emission in CaF2:Yb3+, Tb3+
    Guo, Junjie
    Dong, Yanhui
    Li, Yangyang
    Aidilibike, Tuerxun
    Qin, Weiping
    MATERIALS RESEARCH EXPRESS, 2017, 4 (11):
12345