Molecular Diversity of Sea Spray Aerosol Particles: Impact of Ocean Biology on Particle Composition and Hygroscopicity

被引：127

作者：

Cochran, Richard E. ^{[1
]}

Laskina, Olga ^{[2
]}

Trueblood, Jonathan V. ^{[1
]}

Estillore, Armando D. ^{[1
]}

Morris, Holly S. ^{[2
]}

Jayarathne, Thilina ^{[2
]}

Sultana, Camille M. ^{[1
]}

Lee, Christopher ^{[1
]}

Lin, Peng ^{[3
,4
]}

Laskin, Julia ^{[3
,4
]}

Laskin, Alexander ^{[3
,4
]}

Dowling, Jacqueline A. ^{[2
]}

Qin, Zhen ^{[2
]}

Cappa, Christopher D. ^{[5
]}

Bertram, Timothy H. ^{[6
]}

Tivanski, Alexei V. ^{[2
]}

Stone, Elizabeth A. ^{[2
]}

Prather, Kimberly A. ^{[1
]}

Grassian, Vicki H. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

[2] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA

[3] Pacific Northwest Natl Lab, William R Wiley Environm Mol Sci Lab, Richland, WA 99354 USA

[4] Pacific Northwest Natl Lab, Div Phys Sci, Richland, WA 99354 USA

[5] Univ Calif Davis, Dept Civil & Environm Engn, Davis, CA 95616 USA

[6] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

CHEM | 2017年 / 2卷 / 05期

基金：

美国国家科学基金会;

关键词：

ORGANIC-MATTER ENRICHMENT; FATTY-ACIDS; SURFACE MICROLAYERS; SUBSTANCES EPS; MARINE; LIPIDS; SALT; LIPOPOLYSACCHARIDE; POLYSACCHARIDES; CHEMISTRY;

D O I：

10.1016/j.chempr.2017.03.007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The impact of sea spray aerosol (SSA) on climate depends on the size and chemical composition of individual particles that make up the total SSA ensemble. There remains a lack of understanding as to the composition of individual particles within the SSA ensemble and how it changes in response to dynamic ocean biology. Here, we characterize the classes of organic compounds as well as specific molecules within individual SSA particles. The diversity of molecules within the organic fraction was observed to vary between submicrometer- and supermicrometer-sized particles and included contributions from fatty acids, monosaccharides, polysaccharides, and siliceous material. Significant changes in this molecular diversity were observed to coincide with the rise and fall of phytoplankton and heterotrophic bacteria populations within the seawater. Furthermore, the water uptake of individual particles was affected, as learned from studying the hygroscopicity of model systems composed of representative mixtures of salts and organic compounds.

引用

页码：655 / 667

页数：13

共 50 条

[21] Determining the dependence of size fractionation and oxidative aging on hygroscopicity and phase state of sea spray aerosol
Tumminello, Paul
Mayer, Kathryn
Or, Victor
Cooper, Adam
Grassian, Vicki
Prather, Kimberly
Slade, Jonathan
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
[22] Sea spray aerosol as a unique source of ice nucleating particles
DeMott, Paul J.
Hill, Thomas C. J.
McCluskey, Christina S.
Prather, Kimberly A.
Collins, Douglas B.
Sullivan, Ryan C.
Ruppel, Matthew J.
Mason, Ryan H.
Irish, Victoria E.
Lee, Taehyoung
Hwang, Chung Yeon
Rhee, Tae Siek
Snider, Jefferson R.
McMeeking, Gavin R.
Dhaniyala, Suresh
Lewis, Ernie R.
Wentzell, Jeremy J. B.
Abbatt, Jonathan
Lee, Christopher
Sultana, Camille M.
Ault, Andrew P.
Axson, Jessica L.
Martinez, Myrelis Diaz
Venero, Ingrid
Santos-Figueroa, Gilmarie
Stokes, M. Dale
Deane, Grant B.
Mayol-Bracero, Olga L.
Grassian, Vicki H.
Bertram, Timothy H.
Bertram, Allan K.
Moffett, Bruce F.
Franc, Gary D.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2016, 113 (21) : 5797 - 5803
[23] Sea-spray aerosol particles generated in the surf zone
van Eijk, A. M. J.
Kusmierczyk-Michulec, J. T.
Francius, M. J.
Tedeschi, G.
Piazzola, J.
Merritt, D. L.
Fontana, J. D.
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2011, 116
[24] Impact of Particle Generation Method on the Apparent Hygroscopicity of Insoluble Mineral Particles
Sullivan, Ryan C.
Moore, Meagan J. K.
Petters, Markus D.
Kreidenweis, Sonia M.
Qafoku, Odeta
Laskin, Alexander
Roberts, Greg C.
Prather, Kimberly A.
AEROSOL SCIENCE AND TECHNOLOGY, 2010, 44 (10) : 830 - 846
[25] Effect of biological processes on sea spray aerosol composition and the impact on nitric acid heterogeneous reactivity
Lee, Christopher
Ryder, Olivia
Michaud, Jennifer
Trueblood, Jonathan
Estillore, Armando
Grassian, Vicki
Prather, Kimberly
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
[26] Influence of Organic Acids on the Surface Composition of Sea Spray Aerosol
Unger, Isaak
Saak, Clara-Magdalena
Salter, Matthew
Zieger, Paul
Patanen, Minna
Bjorneholm, Olle
JOURNAL OF PHYSICAL CHEMISTRY A, 2020, 124 (02): : 422 - 429
[27] Acidity across the interface from the ocean surface to sea spray aerosol
Angle, Kyle J.
Crocker, Daniel R.
Simpson, Rebecca M. C.
Mayer, Kathryn J.
Garofalo, Lauren A.
Moore, Alexia N.
Garcia, Stephanie L. Mora
Or, Victor W.
Srinivasan, Sudarshan
Farhan, Mahum
Sauer, Jon S.
Lee, Christopher
Pothier, Matson A.
Farmer, Delphine K.
Martz, Todd R.
Bertram, Timothy H.
Cappa, Christopher D.
Prather, Kimberly A.
Grassian, Vicki H.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2021, 118 (02)
[28] Bringing the ocean into the laboratory to probe the chemical complexity of sea spray aerosol
Prather, Kimberly A.
Bertram, Timothy H.
Grassian, Vicki H.
Deane, Grant B.
Stokes, M. Dale
DeMott, Paul J.
Aluwihare, Lihini I.
Palenik, Brian P.
Azam, Farooq
Seinfeld, John H.
Moffet, Ryan C.
Molina, Mario J.
Cappa, Christopher D.
Geiger, Franz M.
Roberts, Gregory C.
Russell, Lynn M.
Ault, Andrew P.
Baltrusaitis, Jonas
Collins, Douglas B.
Corrigan, Craig E.
Cuadra-Rodriguez, Luis A.
Ebben, Carlena J.
Forestieri, Sara D.
Guasco, Timothy L.
Hersey, Scott P.
Kim, Michelle J.
Lambert, William F.
Modini, Robin L.
Mui, Wilton
Pedler, Byron E.
Ruppel, Matthew J.
Ryder, Olivia S.
Schoepp, Nathan G.
Sullivan, Ryan C.
Zhao, Defeng
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2013, 110 (19) : 7550 - 7555
[29] Sea Spray Aerosol: Where Marine Biology Meets Atmospheric Chemistry
Schiffer, Jamie M.
Mael, Liora E.
Prather, Kimberly A.
Amaro, Rommie E.
Grassian, Vicki H.
ACS CENTRAL SCIENCE, 2018, 4 (12) : 1617 - 1623
[30] Composition and hygroscopicity of aerosol particles at Mt. Lu in South China: Implications for acid precipitation
Li, Weijun
Chi, Jianwei
Shi, Zongbo
Wang, Xinfeng
Chen, Bin
Wang, Yan
Li, Tao
Chen, Jianmin
Zhang, Daizhou
Wang, Zifa
Shi, Chune
Liu, Liangke
Wang, Wenxing
ATMOSPHERIC ENVIRONMENT, 2014, 94 : 626 - 636

← 1 2 3 4 5 →