Radical ring-opening polymerization

被引：0
|
作者：
Sanda, F
Endo, T
机构：
[1] Yamagata Univ, Fac Engn, Dept Polymer Sci & Engn, Yonezawa, Yamagata 9928510, Japan
[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2001年 / 39卷 / 02期
关键词：
radical; ring-opening polymerization; cyclic monomer;
D O I：
10.1002/1099-0518(20010115)39:2<265::AID-POLA20>3.3.CO;2-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The radical ring-opening polymerization (RROP) behavior of the following monomers is reviewed, and the possibility for application to functional materials is described: cyclic disulfide, bicyclobutane. vinylcyclopropane, vinylcyclobutane, vinyloxirane, vinylthiirane, 4-methylene-1,3-dioxolane, cyclic ketene acetal, cyclic arylsulfide, cyclic alpha -oxyacrylate, benzocyclobutene, o-xylylene dimer, exo-methylene-substituted spiro orthocarbonate, exo-methylene-substituted spiro orthoester, and vinylcyclopropanone cyclic acetal. RROP is a promising candidate for producing a wide variety of environmentally friendly functional polymers. (C) 2000 John Wiley & Sons, Inc.
引用
收藏
页码：265 / 276
页数：12
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