Thermochemistry of CuCl2 Dissolution in a Water-2-Propanol-NaCl Mixture at 298.15 K

被引：0
|
作者：
Manin, N. G. [1 ]
机构：
[1] Russian Acad Sci, Inst Solut Chem, Ivanovo 153045, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 06期
关键词：
WATER; ELECTROLYTE; NICKEL(II); COPPER(II); COMPLEXES; IONS;
D O I：
10.1134/S0036023610060239
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The enthalpies of solution of CuCl2 (m < 0.07 mol per kg of the solvent) in a water-2-propanol-NaCl mixture at a NaCl content from 0 to 5 mol % and a 2-propanol content from 0 to 40 mol % were determined by calorimetry at 298.15 K. The effect of the electrolyte and organic component on the solvation of CuCl2 is discussed.
引用
收藏
页码：970 / 976
页数：7
相关论文
共 50 条
  • [31] Facile and diverse microwave-assisted synthesis of secondary propargylamines in water using CuCl/CuCl2
    Tran Thi Thu Trang
    Ermolat'ev, Denis S.
    Van der Eycken, Erik V.
    RSC ADVANCES, 2015, 5 (37) : 28921 - 28924
  • [32] On the formation method of the following composites; (CH2)-H-2((CuCl2)-Cl-2)(KCL)-K-2, (CH2)-H-2[((CuCl2)-Cl-2)(KCL)-K-2](2)
    Chavastelon
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES, 1900, 131 : 48 - 50
  • [33] Gibbs energy and conductivity properties of NaCl solutions in water plus iso-propanol mixtures at 298.15K
    Gregorowicz, J
    Szejgis, A
    Bald, A
    PHYSICS AND CHEMISTRY OF LIQUIDS, 1996, 32 (03) : 133 - 142
  • [34] Crystal-water-induced switching of magnetically active orbitals in CuCl2
    Schmitt, M.
    Janson, O.
    Schmidt, M.
    Hoffmann, S.
    Schnelle, W.
    Drechsler, S. -L.
    Rosner, H.
    PHYSICAL REVIEW B, 2009, 79 (24)
  • [35] Dynamics of excitons and biexcitons in CuCl nanocrystals embedded in NaCl at 2 K
    Yano, S
    Goto, T
    Itoh, T
    Kasuya, A
    PHYSICAL REVIEW B, 1997, 55 (03): : 1667 - 1672
  • [36] Liquid-liquid equilibrium for the ternary systems water+2-methyl-1-propanol + butyl acetate and water+2-methyl-2-propanol + butyl acetate at (298.15 and 323.15) K
    Xu, Dongmei
    Wu, Chunxia
    Zhang, Qing
    Zhang, Huan
    Wang, Yinglong
    Gao, Jun
    FLUID PHASE EQUILIBRIA, 2014, 381 : 60 - 66
  • [37] Catalytic hydroxylation of 1-propanol by platinum NCN and PCP pincer complexes using CuCl2 as oxidant
    Wang, Z
    Sugiarti, S
    Morales, CM
    Jensen, CA
    Morales-Morales, D
    INORGANICA CHIMICA ACTA, 2006, 359 (06) : 1923 - 1928
  • [38] Ternary excess molar enthalpies for methanol or ethanol+1-propanol+2-propanol at the temperature 298.15 K
    Tamura, K
    Saito, M
    Yamada, T
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (03): : 626 - 630
  • [39] Thermochemistry of solvation and complexation in the Cu(NO3)2-water-ethanol-L-α-alanine system at 298.15 K
    V. N. Vandyshev
    Russian Journal of Inorganic Chemistry, 2012, 57 : 297 - 302
  • [40] Thermochemistry of solvation and complexation in the Cu(NO3)2-water-ethanol-L-α-alanine system at 298.15 K
    Vandyshev, V. N.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2012, 57 (02) : 297 - 302
12345