2,5-Bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione

被引：3
|
作者：
Ueda, Kazumasa [1 ,2 ]
Suzuki, Kenta [2 ]
Kunimoto, Kei [2 ]
Yoza, Kenji [3 ]
机构：
[1] Shizuoka Univ, Fac Engn, Div Basic Engn, Hamamatsu, Shizuoka 4328561, Japan
[2] Shizuoka Univ, Grad Sch Engn, Dept Mat Sci & Chem Engn, Hamamatsu, Shizuoka 4328561, Japan
[3] Bruker AXS Co Ltd, Kanagawa Ku, Kanagawa 2210022, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
关键词：
FE(III) D-SPINS; 5-(4,5-DIIODO-1,3-DITHIOL-2-YLIDENE)-4',5'-BIS(METHYLSULFANYL)-2,2'-BI-1,3-DITHI; IONS; CL; BR;
D O I：
10.1107/S1600536811051518
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, C9H4S7, contains two independent molecules, in one of which the central five-membered ring is disordered over two orientations in a 0.924 (3):0.076 (3) ratio. The molecular skeleton is almost planar: the average distance of the atoms from their mean plane is 0.128 (7) angstrom in the ordered molecule, and 0.088 (5) and 0.123 (2) angstrom in the major and minor disorder components, respectively. The ordered and disordered molecules form separate columns by stacking along the b axis. Adjacent columns interact via short S center dot center dot center dot S [3.33 (2), 3.434 (3), 3.444 (2), 3.503 (2), 3.519 (3) and 3.53 (4) angstrom] and S center dot center dot center dot H [2.814 (2), 2.87 (7), 2.92 (2), 2.9269 (18), 2.93 (2), 2.94 (2), 2.939 (2), 2.967 (2) and 2.974 (1) angstrom] contacts.
引用
收藏
页码：O52 / +
页数：12
相关论文
共 50 条
  • [21] Synthesis and nitrosation reactions of π-extended 1,3-dithiol-2-ylidene systems
    Bryce, MR
    Chalton, MA
    Chesney, A
    Catterick, D
    Yao, JW
    Howard, JAK
    TETRAHEDRON, 1998, 54 (15) : 3919 - 3928
  • [22] Bis(1,3-dithiol-2-ylidene)-[3.3]paracyclophanes: orthogonal intramolecular charge transfer interaction
    Sako, Katsuya
    Mase, Yukiharu
    Kato, Yousuke
    Iwanaga, Tetsuo
    Shinmyozu, Teruo
    Takemura, Hiroyuki
    Ito, Mitsuhiro
    Sasaki, Kousuke
    Tatemitsu, Hitoshi
    TETRAHEDRON LETTERS, 2006, 47 (51) : 9151 - 9154
  • [23] Observation of molecular layers in (2-(4,5-bis(thiomethyl)-1,3-dithiol-2-ylidene)-5- (4,5-ethylenedithio-1,3-dithiol-2-ylidene) -1,3,4,6-tetrathiapentalene) (TMET-TTP) single crystals by means of scanning tunneling microscopy
    Takahashi, Teruo
    Mori, Takehiko
    Ishikawa, Ken
    Takezoe, Hideo
    Fukuda, Atsuo
    Misaki, Yohji
    Yamabe, Tokio
    Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes & Review Papers, 1996, 35 (1 A): : 234 - 241
  • [24] Observation of molecular layers in (2-(4,5-bis(thiomethyl)-1,3-dithiol-2-ylidene)-5-(4,5-ethylenedithio-1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene) (TMET-TTP) single crystals by means of scanning tunneling microscopy
    Takahashi, T
    Mori, T
    Ishikawa, K
    Takezoe, H
    Fukuda, A
    Misaki, Y
    Yamabe, T
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1996, 35 (1A): : 234 - 241
  • [25] SYNTHESIS AND PROPERTIES OF STABLE QUINONE METHIDES IMINES, 4-(1,3-DITHIOL-2-YLIDENE)-2,5-CYCLOHEXADIEN-1-IMINES
    NAKAYAMA, J
    MATSUMARU, N
    HOSHINO, M
    TAKEMASA, T
    HETEROCYCLES, 1978, 9 (01) : 127 - 127
  • [26] Manganese(II) complexes coordinated by a new derivative of bipyridine:: 9′-[4,5-Bis(methylthio)-1,3-dithiol-2-ylidene]-4′,5′-diazafluorene
    Zhu, QY
    Dai, J
    Jia, DX
    Cao, LH
    Lin, HH
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (24) : 4789 - 4794
  • [27] STUDIES ON HETEROCYCLIC CATION SYSTEMS .6. SYNTHESES OF 1,3-DITHIOL-2-YLIDENE AND 1,3-OXATHIOL-2-YLIDENE DERIVATIVES
    HIRAI, K
    ISHIBA, T
    SUGIMOTO, H
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1972, 20 (08) : 1711 - +
  • [28] PREPARATION AND PROPERTIES OF NOVEL POLYTHIOPHENES CONTAINING 1,3-DITHIOL-2-YLIDENE MOIETIES
    KOZAKI, M
    TANAKA, S
    YAMASHITA, Y
    JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (02): : 442 - 450
  • [29] 4,5-Bis(ferrocenylmethylthio)-1,3-dithiol-2-one
    Chohan, Z
    Howie, RA
    Wardell, JL
    Low, JN
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 : E46 - E46
  • [30] Synthesis, Characterization and Crystal Structure of 4,5-Bis(Cyclohexanecarbonylthio)-1,3-dithiolane-2-thione Crystal
    Yan Ling Wang
    Mei Li
    Jun Yao
    Ye Fei Wang
    Jing Jing Zheng
    Li Ma
    Journal of Chemical Crystallography, 2010, 40 : 501 - 504
12345