2,5-Bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione

被引：3
|
作者：
Ueda, Kazumasa [1 ,2 ]
Suzuki, Kenta [2 ]
Kunimoto, Kei [2 ]
Yoza, Kenji [3 ]
机构：
[1] Shizuoka Univ, Fac Engn, Div Basic Engn, Hamamatsu, Shizuoka 4328561, Japan
[2] Shizuoka Univ, Grad Sch Engn, Dept Mat Sci & Chem Engn, Hamamatsu, Shizuoka 4328561, Japan
[3] Bruker AXS Co Ltd, Kanagawa Ku, Kanagawa 2210022, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
关键词：
FE(III) D-SPINS; 5-(4,5-DIIODO-1,3-DITHIOL-2-YLIDENE)-4',5'-BIS(METHYLSULFANYL)-2,2'-BI-1,3-DITHI; IONS; CL; BR;
D O I：
10.1107/S1600536811051518
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, C9H4S7, contains two independent molecules, in one of which the central five-membered ring is disordered over two orientations in a 0.924 (3):0.076 (3) ratio. The molecular skeleton is almost planar: the average distance of the atoms from their mean plane is 0.128 (7) angstrom in the ordered molecule, and 0.088 (5) and 0.123 (2) angstrom in the major and minor disorder components, respectively. The ordered and disordered molecules form separate columns by stacking along the b axis. Adjacent columns interact via short S center dot center dot center dot S [3.33 (2), 3.434 (3), 3.444 (2), 3.503 (2), 3.519 (3) and 3.53 (4) angstrom] and S center dot center dot center dot H [2.814 (2), 2.87 (7), 2.92 (2), 2.9269 (18), 2.93 (2), 2.94 (2), 2.939 (2), 2.967 (2) and 2.974 (1) angstrom] contacts.
引用
收藏
页码：O52 / +
页数：12
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