Electrochemical synthesis of polypyrrole in ionic liquids

被引:189
|
作者
Pringle, JM
Efthimiadis, J
Howlett, PC
Efthimiadis, J
MacFarlane, DR
Chaplin, AB
Hall, SB
Officer, DL
Wallace, GG
Forsyth, M
机构
[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
[2] Monash Univ, Sch Phys & Mat Engn, Clayton, Vic 3800, Australia
[3] Massey Univ, Nanomat Res Ctr, Palmerston North, New Zealand
[4] Univ Wollongong, Intelligent Polymer Res Inst, Wollongong, NSW 2522, Australia
关键词
polypyrrole; ionic liquids; conducting polymers;
D O I
10.1016/j.polymer.2004.01.006
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Electrochemical synthesis of inherently conducting polymers such as polypyrrole is traditionally performed in a molecular solvent/electrolyte system such acetonitrile/lithium perchlorate. We report the use of ionic liquids 1-butyl-3-methylimidazolium hexafluorophosphate, 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl) amide and N,N-butylmethylpyrrolidinium bis(trifluoromethanesulfonyl) amide, both as the growth medium and as an electrolyte for the electrochemical cycling of polypyrrole films. Use of the ionic liquid as the growth medium results in significantly altered film morphologies and improved electrochemical activities. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1447 / 1453
页数:7
相关论文
共 50 条
  • [31] Electrochemical synthesis of nanowires and macroporous CuSn alloy from ionic liquids
    A. M. Elbasiony
    A. Prowald
    Sherif Zein El Abedin
    Frank Endres
    Journal of Solid State Electrochemistry, 2022, 26 : 783 - 789
  • [32] Electrochemical synthesis of nanowires and macroporous CuSn alloy from ionic liquids
    Elbasiony, A. M.
    Prowald, A.
    El Abedin, Sherif Zein
    Endres, Frank
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2022, 26 (03) : 783 - 789
  • [33] Synthesis of hollow carbon microspheres in ionic liquids and their electrochemical capacitance characteristics
    Zhang, Fei-Bao
    Li, Hu-Lin
    MATERIALS CHEMISTRY AND PHYSICS, 2006, 98 (2-3) : 456 - 458
  • [34] Electrochemical Creeping and Actuation of Polypyrrole in Ionic Liquid
    Kaneto, Keiichi
    Shinonome, Teruyuki
    Tominaga, Kazuo
    Takashima, Wataru
    JAPANESE JOURNAL OF APPLIED PHYSICS, 2011, 50 (09)
  • [35] Electrochemical creeping and actuation of polypyrrole in ionic liquid
    Kaneto, Keiichi
    Shinonome, Teruyuki
    Tominaga, Kazuo
    Takashima, Wataru
    Japanese Journal of Applied Physics, 2011, 50 (9 PART 1):
  • [36] Synthesis in ionic liquids
    Laali, Kenneth K.
    CURRENT ORGANIC SYNTHESIS, 2007, 4 (04) : 352 - 353
  • [37] Synthesis and electrochemical properties of polypyrrole
    Stankovic, R
    Laninovic, V
    Vojnovic, M
    Pavlovic, O
    Krstajic, N
    Jovanovic, SM
    ADVANCED MATERIALS FOR HIGH TECHNOLOGY APPLICATIONS, 1996, 214 : 147 - 154
  • [38] Electrochemical synthesis of polypyrrole nanowires
    Ge, DT
    Wang, JX
    Wang, SC
    Ma, JB
    He, BL
    JOURNAL OF MATERIALS SCIENCE LETTERS, 2003, 22 (11) : 839 - 840
  • [39] Synthesis and electrochemical properties of polypyrrole
    Univ of Belgrade, Belgrade, Yugoslavia
    Mater Sci Forum, (147-154):
  • [40] Electrochemical synthesis of polypyrrole nanowires
    Jérôme, C
    Jérôme, R
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998, 37 (18) : 2488 - 2490