Transition metal complexes with 2-(N-tosylamino)benzaldehyde 1-phthalazinylhydrazone

被引：19

作者：

Popov, L. D. ^{[1
]}

Shcherbakov, I. N. ^{[1
]}

Levchenkov, S. I. ^{[2
]}

Tupolova, Yu. P. ^{[1
]}

Burlov, A. S. ^{[1
]}

Aleksandrov, G. G. ^{[3
]}

Lukov, V. V. ^{[1
]}

Kogan, V. A. ^{[1
]}

机构：

[1] So Fed Univ, Rostov Na Donu, Russia

[2] Russian Acad Sci, So Sci Ctr, Rostov Na Donu, Russia

[3] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 37卷 / 07期

关键词：

MAGNETIC EXCHANGE; COPPER(II); CRYSTAL; HYDRAZONES; CHEMISTRY; TRENDS;

D O I：

10.1134/S1070328411060078

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2-(N-Tosylamino)benzaldehyde 1-phthalazinylhydrazone (H2L) and its complexes with Cu(II), Ni(II), and Mn(II) were obtained. The acid-basic properties of the hydrazone were studied using potentiometry and spectrophotometry. The experimental data were compared with the results of quantum-chemical DFT calculations. The structure of the binuclear complex [Cu2L2] was determined using X-ray diffraction. The broken symmetry approach was used to calculate the exchange coupling constant of the copper ions.

引用

页码：483 / 491

页数：9

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