Synthesis and Kinetic Modeling of Biomass-Derived Renewable Polyesters

被引:29
|
作者
Lomeli-Rodriguez, Monica [1 ]
Martin-Molina, Miguel [1 ]
Jimenez-Pardo, Maria [1 ]
Nasim-Afzal, Zahara [1 ]
Cauet, Solene I. [1 ]
Davies, Thomas E. [1 ]
Rivera-Toledo, Martin [2 ]
Lopez-Sanchez, Jose A. [1 ]
机构
[1] Univ Liverpool, Stephenson Inst Renewable Energy, Dept Chem, Crown St, Liverpool L69 7ZD, Merseyside, England
[2] Univ Iberoamer, Dept Ingn & Ciencias Quim, Prolongac Paseo Reforma 880, Mexico City 01210, DF, Mexico
基金
英国工程与自然科学研究理事会;
关键词
2,5-furandicarboxylic acid; biomass-derived polymer; renewable polymer; polyesters; succinic acid; SUCCINATE) BIODEGRADABLE POLYESTERS; SELECTIVE AEROBIC OXIDATION; POLYESTERIFICATION REACTIONS; 2,5-FURANDICARBOXYLIC ACID; POLY(ETHYLENE-TEREPHTHALATE) SYNTHESIS; ESTERIFICATION PROCESS; UNSATURATED POLYESTER; 1,2-PROPYLENE GLYCOL; MALEIC-ANHYDRIDE; RESOURCES;
D O I
10.1002/pola.28173
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The biomass-derived polyesters poly(1,3-propylene 2,5-furandicarboxylate) (PPF), poly(1,3-propylene succinate) (PPS) and poly(1,3-propylene 2,5-furandicarboxylate-co-1,3-propylene succinate) (PPFPS) have been synthesized via a twostep process involving polycondensation and azeotropic distillation. The kinetic parameters were obtained by fitting the experimental data from a batch polymerization reactor to three different kinetic models for polyesterification reactions. The activation energies of the all monomer systems were obtained by Arrhenius plots. Given the increasing availability of biomassderived monomers their use in renewable polyesters as substitutes for fossil fuel derived chemicals becomes a distinct possibility. The kinetic modeling of the uncatalyzed polyesterification reactions will enable further integrative process simulation of the studied bioderived polymers and provide a reference for future practical study or industrial applications of catalyzed polyesterification reactions and other bioderived monomer systems. (C) 2016 The Authors. Journal of Polymer Science Part A: Polymer Chemistry Published by Wiley Periodicals, Inc.
引用
收藏
页码:2876 / 2887
页数:12
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