Low-Cost TiS2 as Hole-Transport Material for Perovskite Solar Cells

被引：54

作者：

Huckaba, Aron J. ^{[1
]}

Gharibzadeh, Saba ^{[2
]}

Ralaiarisoa, Maryline ^{[3
,4
]}

Roldan-Carmona, Cristina ^{[1
]}

Mohammadian, Nasim ^{[2
]}

Grancini, Giulia ^{[1
]}

Lee, Yonghui ^{[1
]}

Amsalem, Patrick ^{[3
,4
]}

Plichta, Edward J. ^{[5
]}

Koch, Norbert ^{[3
,4
]}

Moshaii, Ahmad ^{[2
]}

Nazeeruddin, Mohammad Khaja ^{[1
]}

机构：

[1] EPFL Valais, Inst Chem Sci & Engn, GMF, Rue Ind, CH-1951 Sion, Switzerland

[2] Tarbiat Modares Univ, Dept Phys, POB 14115-175, Tehran, Iran

[3] Humboldt Univ, Inst Phys, Brook Taylor Str 6, D-12489 Berlin, Germany

[4] Humboldt Univ, IRIS Adlershof, Brook Taylor Str 6, D-12489 Berlin, Germany

[5] US Army RDECOM CERDEC CP&I, RDER CCA, 5100 Magazine Rd RDER CCA, Aberdeen Proving Ground, MD 21005 USA

来源：

SMALL METHODS | 2017年 / 1卷 / 10期

关键词：

hole-transport materials; nanoparticles; perovskite solar cells; titanium disulfide; transition-metal dichalcogenides; HALIDE PEROVSKITES; ELECTRONIC-STRUCTURE; METAL CHALCOGENIDE; HIGH-PERFORMANCE; V HYSTERESIS; LAYER; EFFICIENCY; RECOMBINATION; TRIHALIDE; DEPOSITION;

D O I：

10.1002/smtd.201700250

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A room-temperature low-cost TiS2 p-type contact material is applied for the first time as the hole-transporting material (HTM) in perovskite solar cells, with power conversion efficiencies surpassing 13.5%. Synthesized by a simple two-step hot-injection method, it presents a much lower price per m(2) than octakis(4-methoxyphenyl)-9,9'-spirospirobi[9H-fluorene]-2,2', 7,7'-tetramine (spiro-OMeTAD), 30 times lower in price ($0.046 for TiS2 and $1.36 for spiro-OMeTAD at 13.54% efficiency), standing out over most of the reported HTM alternatives.

引用

页数：8

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