Transport of organochlorine pesticides in soil columns enhanced by dissolved organic carbon

被引:27
|
作者
Ding, JY
Wu, SC
机构
[1] Grad. Inst. of Environ. Engineering, National Taiwan University, Taipei 10770
关键词
dissolved organic carbon (DOC); humic acid; hydrophobic organic contaminants; organochlorine pesticides (OCPs); soil column; partition coefficient; three-phase transport model;
D O I
10.1016/S0273-1223(97)00124-8
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The objective of this study is to quantify the effects of humic acid solution infiltration on the transport of organochlorine pesticides (OCPs) in soil columns using a three-phase transport model. From experimental results, it is found that the dissolved organic carbon enhances the transport of OCPs in the soil columns. In the OCPs-only column, the concentration profiles of OCPs can be simulated well using a two-phase transport model with numerical method or analytical solution. In the OCPs-DOC column, the migrations of aldrin, DDT and its daughter compounds are faster than those in the OCPs-only column. The simulation with the three-phase model is more accurate than that with the two-phase model. in addition, significant decrease of the fluid pore velocities of the OCPs-DOC column was found. When DOC leachate is applied for remediation of soil or groundwater pollution, the decrease of mean pore velocities will be a crucial affecting factor. (C) 1997 IAWQ. Published by Elsevier Science Ltd.
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页码:139 / 145
页数:7
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