Five new eremophilane sesquiterpenes from Ligularia przewalskii

被引:17
|
作者
Xu, Ji-Qing [1 ]
Hu, Li-Hong [1 ,2 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai Res Ctr Modernizat Tradit Chinese Med, Shanghai 201203, Peoples R China
[2] E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China
关键词
D O I
10.1002/hlca.200890101
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Five new eremophilane-type sesquiterpenes, 3 beta-(acetyloxy)-7-hydroxynoreremophila-6,9-dien-8-one (1), 8 beta-hydroxy-2-dehydroxyliguhodgsonal (2), 3 beta-(acetyloxy)-11-methoxy-8-oxoeremophila-6,9-dien-12-oic acid (3), 3 beta-(acetyloxy)-11-(2'-methylbutanoyloxy)-8-oxoeremophila-6,9-dien-12-oic acid (4), and 3 beta-(acetyloxy)-6 alpha-hydroxyligularenolide (5), along with the three known compounds 6 - 8, were isolated from the roots of Ligularia przewalskii. The structures of the new compounds were elucidated through spectral studies including HR-EI-MS, IR, and NMR data.
引用
收藏
页码:951 / 957
页数:7
相关论文
共 50 条
  • [31] New sesquiterpenes from two Ligularia species
    Peng, HR
    Shi, YP
    Jia, ZJ
    PLANTA MEDICA, 1997, 63 (04) : 335 - 338
  • [32] Two new sesquiterpenes from Ligularia dictyoneura
    Li, Sha
    Huang, Hai
    Liu, Jing
    Song, Tao
    Wu, Kai
    Han, Yifeng
    Xia, Min
    PHYTOCHEMISTRY LETTERS, 2013, 6 (03) : 315 - 317
  • [33] Two new sesquiterpenes from Ligularia veitchiana
    Wang, Y
    Yuan, CS
    Han, YF
    Jia, ZJ
    CHINESE CHEMICAL LETTERS, 2002, 13 (11) : 1069 - 1070
  • [34] Two new sesquiterpenes from Ligularia lankongensis
    Tan, Ai-Min
    He, Hong-Ping
    Zhang, Mian
    Wang, Zheng-Tao
    Hao, Xiao-Jiang
    HELVETICA CHIMICA ACTA, 2007, 90 (01) : 101 - 104
  • [35] New sesquiterpenes from the roots of Ligularia dentata
    Gao, K
    Yang, L
    Jia, ZJ
    PLANTA MEDICA, 1997, 63 (05) : 461 - 463
  • [36] Two new sesquiterpenes from Ligularia duciformis
    Gao, K
    Jia, ZJ
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 1999, 15 (01) : 70 - 72
  • [37] Two New Sesquiterpenes from Ligularia Duciformis
    GAO Kun and JIA Zhong jian ** (Department of Chemistry
    ChemicalResearchinChineseUniversities, 1999, (01) : 72 - 74
  • [38] Two New Sesquiterpenes from Ligularia veitchiana
    Ying WANG
    ChineseChemicalLetters, 2002, (11) : 1069 - 1070
  • [39] Two New Sesquiterpenes from Ligularia macrophylla
    Tong SHEN
    Chinese Chemical Letters, 2005, (09) : 1220 - 1222
  • [40] FOUR NEW SESQUITERPENES FROM LIGULARIA VIRGAUREA
    Hong Ming CHEN and Zhong Jian JIA~② Institute of Organic Chemistry
    ChineseChemicalLetters, 1991, (11) : 849 - 852