Differences in actinide metal-ligand orbital interactions: comparison of U(IV) and Pu(IV) β-ketoiminate N,O donor complexes

被引：23

作者：

Schnaars, David D. ^{[2
,3
]}

Batista, Enrique R. ^{[1
]}

Gaunt, Andrew J. ^{[3
]}

Hayton, Trevor W. ^{[2
]}

May, Iain ^{[3
]}

Reilly, Sean D. ^{[3
]}

Scott, Brian L. ^{[4
]}

Wu, Guang ^{[2
]}

机构：

[1] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA

[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

[3] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

[4] Los Alamos Natl Lab, Mat Phys & Applicat Div, Los Alamos, NM 87545 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 27期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1039/c1cc12409a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Syntheses and characterization of UCl2((Ar)acnac)(2), UI2((Ar)acnac)(2), and PuI2((Ar)acnac)(2) are reported ((Ar)acnac denotes a bis-phenyl beta-ketoiminate ligand where Ar = 3,5-(Bu2C6H3)-Bu-t). Structural analyses and computations show significant metal-ligand orbital interaction differences in U(IV) vs. Pu(IV) bonding.

引用

页码：7647 / 7649

页数：3

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