Kinetic studies of Cl reactions with 3-buten-1-ol and 2-buten-1-ol over the temperature range 298-363 K

被引：9

作者：

Liang, P. ^{[1
,2
]}

Mu, Y. J. ^{[1
]}

Daele, V. ^{[2
]}

Mellouki, A. ^{[2
]}

机构：

[1] CAS, RCEES, Beijing 100085, Peoples R China

[2] CNRS, ICARE, F-45071 Orleans 02, France

来源：

CHEMICAL PHYSICS LETTERS | 2011年 / 502卷 / 4-6期

关键词：

GAS-PHASE REACTIONS; VOLATILE ORGANIC-COMPOUNDS; UNSATURATED ALCOHOLS; ATMOSPHERIC CHEMISTRY; ATOMIC CHLORINE; RATE CONSTANTS; OH RADICALS; MOLECULAR CHLORINE; N-2/O-2; DILUENT; MECHANISM;

D O I：

10.1016/j.cplett.2010.12.058

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using the relative rate method, the rate coefficients for gas phase reactions of Cl atoms with two unsaturated alcohols, 3-buten-1-ol (k(1)) and 2-buten-1-ol (k(2)), were determined in 760 Torr of purified air over the temperature range of 298-363 K. At 298 K, the measured rate coefficients (in units of cm(3) molecule (1) s (1)) were found to be: k(1) = (2.63 +/- 0.25) x 10 (10) and k(2) = (3.90 +/- 0.35) x 10 (10). The values obtained are discussed and compared with the previous determinations. (C) 2010 Elsevier B.V. All rights reserved.

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页码：154 / 158

页数：5

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