Kinetic studies of Cl reactions with 3-buten-1-ol and 2-buten-1-ol over the temperature range 298-363 K

被引：9
|
作者：
Liang, P. [1 ,2 ]
Mu, Y. J. [1 ]
Daele, V. [2 ]
Mellouki, A. [2 ]
机构：
[1] CAS, RCEES, Beijing 100085, Peoples R China
[2] CNRS, ICARE, F-45071 Orleans 02, France
来源：
CHEMICAL PHYSICS LETTERS | 2011年 / 502卷 / 4-6期
关键词：
GAS-PHASE REACTIONS; VOLATILE ORGANIC-COMPOUNDS; UNSATURATED ALCOHOLS; ATMOSPHERIC CHEMISTRY; ATOMIC CHLORINE; RATE CONSTANTS; OH RADICALS; MOLECULAR CHLORINE; N-2/O-2; DILUENT; MECHANISM;
D O I：
10.1016/j.cplett.2010.12.058
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Using the relative rate method, the rate coefficients for gas phase reactions of Cl atoms with two unsaturated alcohols, 3-buten-1-ol (k(1)) and 2-buten-1-ol (k(2)), were determined in 760 Torr of purified air over the temperature range of 298-363 K. At 298 K, the measured rate coefficients (in units of cm(3) molecule (1) s (1)) were found to be: k(1) = (2.63 +/- 0.25) x 10 (10) and k(2) = (3.90 +/- 0.35) x 10 (10). The values obtained are discussed and compared with the previous determinations. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：154 / 158
页数：5
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