Ballistic Fracturing of Carbon Nanotubes

被引:18
|
作者
Ozden, Sehmus [1 ]
Machado, Leonardo D. [2 ,3 ]
Tiwary, ChandraSekhar [1 ]
Autreto, Pedro A. S. [2 ,4 ]
Vajtai, Robert [1 ]
Barrera, Enrique V. [1 ]
Galvao, Douglas S. [2 ]
Ajayan, Pulickel M. [1 ]
机构
[1] Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
[2] Univ Estadual Campinas, Dept Appl Phys, BR-13083959 Campinas, SP, Brazil
[3] Univ Fed Rio Grande do Norte, Dept Fis Teor & Expt, BR-59072970 Natal, RN, Brazil
[4] Univ Fed ABC, BR-09210580 Santo Andre, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
high impact; unzipping; carbon nanotubes; junction; MD simulation; REACTIVE FORCE-FIELD; MOLECULAR-DYNAMICS; COMPOSITES; IMPACT; SCIENCE; REAXFF;
D O I
10.1021/acsami.6b07547
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Advanced materials with multifunctional capabilities and high resistance to hypervelocity, impact are of great interest to the designers of aerospace structures. Carbon nanotubes (CNTs) with their lightweight and high strength properties are alternative-to metals and/or metallic alloys conventionally used in aerospace-applications. Here we report, a detailed study on the ballistic fracturing of CNTs for different velocity ranges. Our-results show that the highly energetic impacts cause bond breakage and carbon atom rehybridizations, and sometimes extensive structural reconstructions were also observed Experimental;, observations Show the formation of nanoribbons,, nanodiamonds, and covalently interconnected nanostructures, depending On impact conditions. Fully atotnistic reactive molecular dynamics simulations were also carried out in order to gain further insights into the mechanism behind the transformation of CNTs. The simulations show that the velocity and relative-orientation of the multiple colliding :nanotubes are critical to determine the impact outcome.
引用
收藏
页码:24819 / 24825
页数:7
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