The effects of Ge partial substitution for Si on the thermoelectric properties of CoSi1-xGex alloys were investigated by means of thermal and electrical transport measurements. Electrical resistivity (rho), Seebeck coefficient (S), and thermal conductivity (kappa) measurements were performed on a series of CoSi1-xGex alloys with x varying from 0 to 0.15. A substantial decrease in electrical resistivity and lattice thermal conductivity was noticed with increasing substitution level, whereas the Seebeck coefficient shows a weak variation with respect to Ge concentration. The thermoelectric efficiency was found to be enhanced by an order of magnitude in CoSi with Ge substitution. These observations were interpreted on the basis of the changes in the electronic band structure induced by Ge substitution. (c) 2005 American Institute of Physics.
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Pontificia Univ Catolica Rio de Janeiro, Dept Fis, BR-38071970 Rio De Janeiro, BrazilPontificia Univ Catolica Rio de Janeiro, Dept Fis, BR-38071970 Rio De Janeiro, Brazil
Peche, L
Anda, EV
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机构:Pontificia Univ Catolica Rio de Janeiro, Dept Fis, BR-38071970 Rio De Janeiro, Brazil
Anda, EV
Büsser, CA
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机构:Pontificia Univ Catolica Rio de Janeiro, Dept Fis, BR-38071970 Rio De Janeiro, Brazil
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Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USAUniv Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Li, SX
Haller, EE
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Haller, EE
Yu, KM
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Yu, KM
Walukiewicz, W
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Walukiewicz, W
Ager, JW
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Ager, JW
Wu, J
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Wu, J
Shan, W
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Shan, W
Lu, H
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Lu, H
Schaff, WJ
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机构:Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA