Chemical selectivity through control of excited-state dynamics

被引：35
|
作者：
Olivucci, Massimo [1 ,2 ]
Santoro, Fabrizio [3 ]
机构：
[1] Univ Siena, Dipartimento Chim, I-53100 Siena, Italy
[2] Bowling Green State Univ, Dept Chem, Bowling Green, OH 43403 USA
[3] Ist & Proc Chim Fis, CNR, Area Ric, I-56124 Pisa, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 34期
关键词：
conformation selectivity; conical intersections; orbital alignment; reaction mechanisms; stereodynamics;
D O I：
10.1002/anie.200800898
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Graph Presented) Trust is good, control is better: In thermal processes in which the interconversion of reactant conformers R1/2 is faster than the reaction itself, selectivity can be tailored by modulating the energy barriers of competing reaction paths. Ultrafast photoexcitation promotes separate conformers to different regions of the potential energy surface, where the wave packet may reach different conical intersections CI1/2, giving rise to product selectivity (P1/2). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：6322 / 6325
页数：4
相关论文
共 50 条
  • [21] Excited-state dynamics of astaxanthin aggregates
    Fuciman, Marcel
    Durchan, Milan
    Slouf, Vaclav
    Kesan, Guerkan
    Polivka, Tomas
    CHEMICAL PHYSICS LETTERS, 2013, 568 : 21 - 25
  • [22] EXCITED-STATE LATTICE-DYNAMICS
    DOMINONI, M
    TERZI, N
    JOURNAL OF LUMINESCENCE, 1994, 58 (1-6) : 11 - 13
  • [23] Excited-State Dynamics in CZTS Nanocrystals
    Pundsack, Tom J.
    Chernomordik, Boris D.
    Beland, Amelie E.
    Aydil, Eray S.
    Blank, David A.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (16): : 2711 - 2714
  • [24] EXCITED-STATE DYNAMICS IN RESTRICTED GEOMETRIES
    KLAFTER, J
    DRAKE, JM
    LEVITZ, P
    BLUMEN, A
    ZUMOFEN, G
    JOURNAL OF LUMINESCENCE, 1990, 45 (1-6) : 34 - 39
  • [25] Ultrafast excited-state dynamics of isocytosine
    Szabla, Rafal
    Gora, Robert W.
    Sponer, Jiri
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (30) : 20208 - 20218
  • [26] EXCITED-STATE MOLECULAR PHOTOIONIZATION DYNAMICS
    PRATT, ST
    REPORTS ON PROGRESS IN PHYSICS, 1995, 58 (08) : 821 - 883
  • [27] Laser dynamics with excited-state absorption
    Sanchez, F
    Kellou, A
    JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1997, 14 (01) : 209 - 213
  • [28] Complexity of excited-state dynamics in DNA
    Dimitra Markovitsi
    Francis Talbot
    Thomas Gustavsson
    Delphine Onidas
    Elodie Lazzarotto
    Sylvie Marguet
    Nature, 2006, 441 : E7 - E7
  • [29] POLYSILANE EXCITED-STATES AND EXCITED-STATE DYNAMICS
    THORNE, JRG
    REPINEC, ST
    ABRASH, SA
    ZEIGLER, JM
    HOCHSTRASSER, RM
    CHEMICAL PHYSICS, 1990, 146 (03) : 315 - 325
  • [30] ADVANCES IN CHEMICAL PHYSICS, VOL 50 - DYNAMICS OF THE EXCITED-STATE - LAWLEY,KP
    WOLF, HC
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (11): : 894 - 895
12345