On the measurement of N2(A3Σu+) metastable in N2 surface-dielectric barrier discharge at atmospheric pressure

被引:26
|
作者
Ambrico, P. F. [1 ]
Simek, M. [2 ]
Dilecce, G. [1 ]
De Benedictis, S. [1 ]
机构
[1] CNR, Ist Metodol Inorgan & Plasmi, I-70126 Bari, Italy
[2] Acad Sci Czech Republ, Inst Plasma Phys, Lab Pulse Plasma Syst, Prague 18200, Czech Republic
关键词
atmospheric pressure surface-DBD; nitrogen metastable; LIF; optical emission spectroscopy;
D O I
10.1007/s11090-008-9131-5
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The N-2(A(3)Sigma(+)(u)) metastable has been investigated in an AC surface dielectric barrier discharge (surface-DBD) at atmospheric pressure in N-2 by Optical-Optical Double Resonance-Laser Induced Fluorescence spectroscopy (OODR-LIF) and by Optical Emission Spectroscopy (OES). The discharge is single-side produced by metallic stripes (comb-like electrode on a dielectric layer). The OODR-LIF measurements have been carried out in space afterglow above the plasma layer. The measurement was time resolved during the AC high voltage cycle and space resolved around the metallic/dielectric stripes. The space afterglow N-2(A) density does not evidence significant variation in the voltage cycle. The density is higher above the dielectric strip than on the metallic one. N-2(A) density in the space afterglow has been estimated to be about 10(11) cm(-3). The plasma layer, not accessible by OODR-LIF, has been investigated by OES through NO gamma and Herman infrared bands. The estimated N-2(A) maximum density in the plasma layer is higher than 10(123) cm(-3).
引用
收藏
页码:299 / 316
页数:18
相关论文
共 50 条
  • [21] A trajectory surface hopping study of N2(A3Σu+) quenching by H atoms
    Borges, Y. G.
    Galvao, B. R. L.
    Mota, V. C.
    Varandas, A. J. C.
    CHEMICAL PHYSICS LETTERS, 2019, 729 : 61 - 64
  • [22] Formation of N2(A3Σu+, v=0-3) metastable species in decaying nitrogen streamer
    Simek, M.
    Ambrico, P. F.
    Prukner, V.
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2013, 46 (48)
  • [23] Evidence for the production of N4 via the N2 A3Σu++N2 A3Σu+ energy pooling reaction
    Barber, J
    Hof, DE
    Meserole, CA
    Funk, DJ
    JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (11): : 3853 - 3856
  • [24] Intracavity laser absorption spectroscopy applied to measure the absolute density and temperature of N2(A 3Σu+) metastable molecules in a flowing N2 microwave discharge
    Foissac, C
    Campargue, A
    Kachanov, A
    Supiot, P
    Weirauch, G
    Sadeghi, N
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2000, 33 (19) : 2434 - 2441
  • [25] Spatio-temporal characterization of N2(A3Σu+) metastables in diffuse nitrogen barrier discharges
    Nemschokmichal, S.
    Meichsner, J.
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2015, 48 (40)
  • [26] Time-resolved populations of N2(A3Σu+,v) in nanosecond pulse discharge plasmas
    Jans, E. R.
    Frederickson, K.
    Miller, T. A.
    Adamovich, I. V.
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2019, 365
  • [27] N2(A3Σu+) metastable density in nitrogen barrier discharges: II. Spatio-temporal behaviour in filamentary mode
    Nemschokmichal, S.
    Meichsner, J.
    PLASMA SOURCES SCIENCE & TECHNOLOGY, 2013, 22 (01):
  • [28] DIELECTRIC BARRIER DISCHARGE PUMPED N2 LASER
    KOHLER, J
    APPLIED OPTICS, 1994, 33 (18): : 3812 - 3815
  • [29] Kinetics of excitation of N2(A3Σu+, vA), N2(C3Πu, vC), and N2(B3Πg, vB) in nitrogen discharge plasmas as studied by means of emission spectroscopy and computer simulation
    Shakhatov, V. A.
    Lebedev, Yu. A.
    HIGH ENERGY CHEMISTRY, 2008, 42 (03) : 170 - 204
  • [30] Kinetics of excitation of N2(A3Σu+, vA), N2(C3Πu, vc), and N2(B3Πg, vB) in nitrogen discharge plasmas as studied by means of emission spectroscopy and computer simulation
    V. A. Shakhatov
    Yu. A. Lebedev
    High Energy Chemistry, 2008, 42 : 170 - 204