Fast and Living Ring-Opening Polymerization of α-Amino Acid N-Carboxyanhydrides Triggered by an "Alliance" of Primary and Secondary Amines at Room Temperature

被引：49
|
作者：
Zhao, Wei [1 ]
Gnanou, Yves [2 ]
Hadjichristidis, Nikos [1 ]
机构：
[1] KAUST, Phys Sci & Engn Div, KAUST Catalysis Ctr, Polymer Synth Lab, Thuwal 23955, Saudi Arabia
[2] KAUST, Phys Sci & Engn Div, Thuwal 23955, Saudi Arabia
来源：
BIOMACROMOLECULES | 2015年 / 16卷 / 04期
关键词：
BLOCK COPOLYPEPTIDES; NCA POLYMERIZATION; POLYPEPTIDES; COPOLYMERS; CHEMISTRY; MECHANISM; KINETICS; STRATEGY;
D O I：
10.1021/acs.biomac.5b00134
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A novel highly efficient strategy, based on an alliance of primary and secondary amine initiators, was successfully developed allowing the fast and living ring-opening polymerization (ROP) of alpha-amino acid N-carboxyanhydrides (NCAs) at room temperature.
引用
收藏
页码：1352 / 1357
页数：6
相关论文
共 50 条
  • [1] Controlled ring-opening polymerization of α-amino acid N-carboxyanhydrides in the presence of tertiary amines
    Vacogne, Charlotte D.
    Schlaad, Helmut
    [J]. POLYMER, 2017, 124 : 203 - 209
  • [2] Synthesis of Polypeptides by Ring-Opening Polymerization of α-Amino Acid N-Carboxyanhydrides
    Cheng, Jianjun
    Deming, Timothy J.
    [J]. PEPTIDE-BASED MATERIALS, 2012, 310 : 1 - 26
  • [3] Novel initiating/organocatalytic systems for the living ring-opening polymerization of α-amino acid N-carboxyanhydrides
    Hadjichristidis, Nikos
    Zhao, Wei
    Gnanou, Yves
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [4] Organosilicon amines mediated controlled ring-opening polymerization of amino acid N-carboxyanhydrides (NCAs) and polypeptides
    Lu, Hua
    Cheng, Jianjun
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
  • [5] Ring-Opening Polymerization of N-Carboxyanhydrides Initiated by a Hydroxyl Group
    Gradisar, Spela
    Zagar, Ema
    Pahovnik, David
    [J]. ACS MACRO LETTERS, 2017, 6 (06): : 637 - 640
  • [6] N-trimethylsilyl amines for controlled ring-opening polymerization of amino acid N-carboxyanhydrides and facile end group functionalization of polypeptides
    Lu, Hua
    Cheng, Jianjun
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (38) : 12562 - +
  • [7] N-trimethylsilyl amines for controlled ring-opening polymerization of amino acid N-carboxyanhydrides and facile end group functionalization of polypeptides
    Lu, Hua
    Cheng, Jianjun
    [J]. Journal of the American Chemical Society, 2008, 130 (38): : 12562 - 12563
  • [8] N-Trimethylsilyl amines for controlled ring-opening polymerization of amino acid N-carboxyanhydrides and facile end group functionalization of polypeptides
    Lu, Hua
    Cheng, Jianjun
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
  • [9] Investigation of α-amino acid N-carboxyanhydrides by X-ray diffraction at, for controlled ring-opening polymerization
    Schaefer, Olga
    Schollmeyer, Dieter
    Birke, Alexander
    Holm, Regina
    Johann, Kerstin
    Muhl, Christian
    Seidl, Christine
    Weber, Benjamin
    Barz, Matthias
    [J]. TETRAHEDRON LETTERS, 2019, 60 (03) : 272 - 275
  • [10] Phenyl Trimethylsilyl Sulfide-Mediated Controlled Ring-Opening Polymerization of α-Amino Acid N-Carboxyanhydrides
    Yuan, Jingsong
    Sun, Yunlong
    Wang, Jingyu
    Lu, Hua
    [J]. BIOMACROMOLECULES, 2016, 17 (03) : 891 - 896
12345