The use of copper catalysts in the hydrogen transfer reduction of 4-tert-butylcyclohexanone

被引：0

作者：

Zaccheria, F ^{[1
]}

Fusi, A ^{[1
]}

Psaro, R ^{[1
]}

Ravasio, N ^{[1
]}

机构：

[1] Consorzio INSTM, I-50132 Florence, Italy

来源：

Catalysis of Organic Reactions | 2005年 / 104卷

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several low loading supported copper catalysts were tested in the hydrogen transfer reduction of 4-tert-butyl-cyclohexanone showing good activity under very mild conditions (2-propanol as solvent, 83 degrees C, N-2). Results obtained by using different alcohols as donors suggest that a two step dehydrogenation-hydrogenation mechanism is operating over Cu/SiO2.

引用

页码：293 / 301

页数：9

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