The use of copper catalysts in the hydrogen transfer reduction of 4-tert-butylcyclohexanone

被引：0
|
作者：
Zaccheria, F [1 ]
Fusi, A [1 ]
Psaro, R [1 ]
Ravasio, N [1 ]
机构：
[1] Consorzio INSTM, I-50132 Florence, Italy
来源：
Catalysis of Organic Reactions | 2005年 / 104卷
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Several low loading supported copper catalysts were tested in the hydrogen transfer reduction of 4-tert-butyl-cyclohexanone showing good activity under very mild conditions (2-propanol as solvent, 83 degrees C, N-2). Results obtained by using different alcohols as donors suggest that a two step dehydrogenation-hydrogenation mechanism is operating over Cu/SiO2.
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页码：293 / 301
页数：9
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