Poly N,N-dimethylaniline-formaldehyde supported on silica-coated magnetic nanoparticles: a novel and retrievable catalyst for green synthesis of 2-amino-3-cyanopyridines

被引：27
|
作者：
Asadbegi, Sajad [1 ]
Bodaghifard, Mohammad Ali [1 ,2 ]
Mobinikhaledi, Akbar [1 ]
机构：
[1] Arak Univ, Fac Sci, Dept Chem, Arak, Iran
[2] Arak Univ, Inst Nanosciences, Nanotechnol, Arak, Iran
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2020年 / 46卷 / 03期
关键词：
2-Amino-3-cyanopyridines; Magnetic nanoparticles; Multi-component reactions; Green synthesis; ONE-POT SYNTHESIS; IRON-OXIDE NANOPARTICLES; PYRIDINE-DERIVATIVES; MULTICOMPONENT; INHIBITORS; MALONONITRILE; EFFICIENT; HETEROCYCLES; CYCLIZATION; DISCOVERY;
D O I：
10.1007/s11164-017-3200-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Preparation and application of novel and reusable magnetic nanoparticles with poly N,N-dimethylaniline-formaldehyde support as a heterogeneous basic catalyst have been described. The reported catalyst was characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction patterns, transmission electron microscopy, energy dispersive X-ray spectroscopy, thermogravimetric analysis and vibrating sample magnetometry. The catalytic performance of this organic-inorganic hybrid nanomaterial has been studied for the green synthesis of 2-amino-3-cyanopyridine derivatives through one-pot four-component reactions. An eco-friendly method, short reaction time, high yield and easy work-up procedure are the advantages of this new methodology over earlier ones.
引用
收藏
页码：1629 / 1643
页数：15
相关论文
共 50 条
  • [31] One-pot synthesis of 2-amino-3-cyanopyridines and hexahydroquinolines using eggshell-based nano-magnetic solid acid catalyst via anomeric-based oxidation
    Tahere Akbarpoor
    Ardeshir Khazaei
    Jaber Yousefi Seyf
    Negin Sarmasti
    Maryam Mahmoudiani Gilan
    Research on Chemical Intermediates, 2020, 46 : 1539 - 1554
  • [32] One-pot synthesis of 2-amino-3-cyanopyridines and hexahydroquinolines using eggshell-based nano-magnetic solid acid catalyst via anomeric-based oxidation
    Akbarpoor, Tahere
    Khazaei, Ardeshir
    Seyf, Jaber Yousefi
    Sarmasti, Negin
    Gilan, Maryam Mahmoudiani
    RESEARCH ON CHEMICAL INTERMEDIATES, 2020, 46 (02) : 1539 - 1554
  • [33] N-propylbenzoguanamine sulfonic acid-functionalized magnetic nanoparticles: A novel and magnetically retrievable catalyst for the synthesis of 1,4-dihydropyridine derivatives
    Dehbalaei, Masoumeh Gholami
    Foroughifar, Naser
    Khajeh-Amiri, Alireza
    Pasdar, Hoda
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2018, 65 (11) : 1356 - 1369
  • [34] Selenium-directed synthesis of Pd nanoparticles on mesoporous silica-coated Fe3O4: An efficient magnetic catalyst for oxidative alkene cracking
    Zhu, Zhida
    Wang, Wenjun
    Zeng, Li
    Zhang, Fan
    Liu, Jingjing
    CATALYSIS COMMUNICATIONS, 2020, 142
  • [35] Ferrocene-tagged ionic liquid stabilized on silica-coated magnetic nanoparticles: Efficient catalyst for the synthesis of 2-amino-3-cyano-4H-pyran derivatives under solvent-free conditions
    Teimuri-Mofrad, Reza
    Gholamhosseini-Nazari, Mahdi
    Payami, Elmira
    Esmati, Somayeh
    APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (01)
  • [36] Phosphotungstic acid supported on silica-coated CoFe2O4 nanoparticles: An efficient and magnetically-recoverable catalyst for N-formylation of amines under solvent-free conditions
    Kooti, M.
    Nasiri, E.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2015, 406 : 168 - 177
  • [37] Silica-coated magnetic NiFe2O4 nanoparticles-supported H3PW12O40; synthesis, preparation, and application as an efficient, magnetic, green catalyst for one-pot synthesis of tetrahydrobenzo[b]pyran and pyrano[2,3-c]pyrazole derivatives
    Behrooz Maleki
    Hossein Eshghi
    Mohammad Barghamadi
    Negar Nasiri
    Amir Khojastehnezhad
    Samaneh Sedigh Ashrafi
    Omid Pourshiani
    Research on Chemical Intermediates, 2016, 42 : 3071 - 3093
  • [38] Silica-coated magnetic NiFe2O4 nanoparticles-supported H3PW12O40; synthesis, preparation, and application as an efficient, magnetic, green catalyst for one-pot synthesis of tetrahydrobenzo[b]pyran and pyrano[2,3-c]pyrazole derivatives
    Maleki, Behrooz
    Eshghi, Hossein
    Barghamadi, Mohammad
    Nasiri, Negar
    Khojastehnezhad, Amir
    Sedigh Ashrafi, Samaneh
    Pourshiani, Omid
    RESEARCH ON CHEMICAL INTERMEDIATES, 2016, 42 (04) : 3071 - 3093
  • [39] One-Pot Synthesis of Novel 3-Pyrazolyl-4H-1,2,4-triazoles Using Amino Glucose‐Functionalized Silica-Coated NiFe2O4 Nanoparticles as a Magnetically Separable Catalyst
    Mohammad Nikpassand
    Mohadeseh Jafari Farshami
    Journal of Cluster Science, 2021, 32 : 975 - 982
  • [40] Novel synthesis of silica-coated Eu:Gd2O3 nanoparticles by polyol route at low temperature for bimodal cancer imaging
    Gayathri, T.
    Kumar, R. Arun
    Panigrahi, B. S.
    Saravanan, P.
    Devanand, B.
    MATERIALS RESEARCH EXPRESS, 2019, 6 (05):
12345