Photocatalytic activity of nano-sized Ag and Au metal-doped TiO2 embedded in rGO under visible light irradiation

被引:19
|
作者
Khairy, M. [1 ,2 ]
Kamar, E. M. [1 ]
Mousa, M. A. [1 ]
机构
[1] Benha Univ, Fac Sci, Chem Dept, Banha, Egypt
[2] Imam Mohammad Ibn Saud Islamic Univ IMSIU, Coll Sci, Chem Dept, Riyadh 11623, Saudi Arabia
关键词
TiO2; Doping; Noble metals; Photocatalytic degradation; Kinetic; Wastewater treatment; DYE DEGRADATION; METHYLENE-BLUE; PERFORMANCE; SOLAR; NANOCOMPOSITE; NANOPARTICLES; PHOTOLUMINESCENCE; NANOSTRUCTURES; SPECTROSCOPY; DEPOSITION;
D O I
10.1016/j.mseb.2022.116023
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study looks at the structural, optical properties, and comparative visible light photocatalytic activity of Ag/ Au-TiO2 doped nanotubes and the impact of embedding them in rGO. The studied materials were characterized using XRD, SEM, TEM, XPS, BET, Raman spectra, diffuse reflectance spectroscopy (DRS), electrochemical impedance spectroscopy (EIS), and open-circuit voltage decay (OCVD), and photocurrent transient response (PCTR). The photocatalytic activity was found to increase in the order TAg,Au/rGO > TAg/rGO > TAu/rGO > TAg,Au > TAg > TAu > TrGO > TiO2 (T). Under optimal conditions, complete MB degradation is achieved in one hour. The kinetics of the photocatalytic reaction followed the first-order relationship. A photocatalytic mecha-nism has been proposed.
引用
收藏
页数:15
相关论文
共 50 条
  • [31] Enhancing effects of water content and ultrasonic irradiation on the photocatalytic activity of nano-sized TiO2 powders
    Yu, JC
    Yu, JG
    Zhang, LZ
    Ho, WK
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 148 (1-3) : 263 - 271
  • [32] Highly photocatalytic activity of novel nano-sized Ag3PO4 for Rhodamine B degradation under visible light irradiation
    Vu, Tuan A.
    Dao, Canh D.
    Hoang, Thuy T. T.
    Nguyen, Kien T.
    Le, Giang H.
    Dang, Phuong T.
    Tran, Hoa T. K.
    Nguyen, Tuyen V.
    MATERIALS LETTERS, 2013, 92 : 57 - 60
  • [33] Comparison of Ag deposition effects on the photocatalytic activity of nanoparticulate TiO2 under visible and UV light irradiation
    Sung-Suh, HM
    Choi, JR
    Hah, HJ
    Koo, SM
    Bae, YC
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 163 (1-2) : 37 - 44
  • [34] Photocatalytic reduction of Cr (VI) on nano-sized red phosphorus under visible light irradiation
    Li, Donghui
    Li, Jiaojiao
    Jin, Qianwei
    Ren, Zhenpeng
    Sun, Yuewei
    Zhang, Ruiqin
    Zhai, Yunpu
    Liu, Yonggang
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2019, 537 : 256 - 261
  • [35] rGO-wrapped Ag-doped TiO2 nanofibers for photocatalytic CO2 reduction under visible light
    Kang, Sangmo
    Hwang, Jungho
    JOURNAL OF CLEANER PRODUCTION, 2022, 374
  • [36] Synthesis of TiO2/Ag2NCN Composite Catalysts and Their Photocatalytic Activity Under Visible Light Irradiation
    Li Xia
    Zhang Xia
    Zhu Zefeng
    Lin Guoqing
    Li Youbin
    Li Xiaoxue
    Xu Junli
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2015, 36 (02): : 361 - 367
  • [37] Novel (Ag,Y) doped TiO2 plasmonic photocatalyst with enhanced photocatalytic activity under visible light
    Kallel, Wannes
    Chaabene, Sirine
    Bouattour, Soraa
    PHYSICOCHEMICAL PROBLEMS OF MINERAL PROCESSING, 2019, 55 (03): : 745 - 759
  • [38] Photophysical properties of nanosized metal-doped TiO2 photocatalyst working under visible light
    Bae, S. W.
    Borse, P. H.
    Hong, S. J.
    Jang, J. S.
    Lee, J. S.
    Jeong, E. D.
    Hong, T. E.
    Yoon, J. H.
    Jin, J. S.
    Kim, H. G.
    JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2007, 51 : S22 - S26
  • [39] Synthesis and photocatalytic activity of sulfate modified Nd-doped TiO2 under visible light irradiation
    孙东峰
    王凯
    徐志坚
    李锐星
    Journal of Rare Earths, 2015, 33 (05) : 491 - 497
  • [40] Electrospun nanofibers of Bi-doped TiO2 with high photocatalytic activity under visible light irradiation
    Xu, Jie
    Wang, Wenzhong
    Shang, Meng
    Gao, Erping
    Zhang, Zhijie
    Ren, Jia
    JOURNAL OF HAZARDOUS MATERIALS, 2011, 196 : 426 - 430