Dichloro{cis-Bis[diphenylborylhydroxymethyl-(acetimidoyl)phenylphosphine]}platinum(II): Synthesis; Molecular and Crystal Structures

被引:0
|
作者
Karasik, A. A. [1 ]
Georgiev, I. O. [1 ]
Litvinov, I. A. [1 ]
Nikonov, G. N. [1 ]
Sinyashin, O. G. [1 ]
机构
[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420083, Tatarstan, Russia
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of diphenylborylhydroxymethyl(acetimidoyl)phenylphosphine with dichloro(1,5-cyclooctadiene)platinum(II) gave the dichloro{cis-bis[diphenylborylhydroxymethyl(acetimidoyl)phenylphosphine]}platinum(II) complex. The molecular and crystal structures of the complex were determined, and the conformational behavior of the heterocyclic ligand in solution was described.
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页码:576 / 581
页数:6
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