Triazole-forming waterborne polyurethane composites fabricated with silane coupling agent functionalized nano-silica

被引:57
|
作者
Sun, Daoxing [1 ,3 ]
Miao, Xiao [1 ]
Zhang, Kejie [2 ]
Kim, Hern [3 ]
Yuan, Yongan [3 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Peoples R China
[2] Nanjing Univ Sci & Technol, Minist Educ, Key Lab Soft Chem & Funct Mat, Nanjing 210094, Peoples R China
[3] Myongji Univ, Dept Environm Engn & Biotechnol, Energy & Environm Fus Technol Ctr, Yongin 449728, Kyonggi Do, South Korea
关键词
Triazole; Click chemistry; Waterborne polyurethane; Nano-silica; CLICK CHEMISTRY; STAR POLYMERS; POLYMERIZATION; RAFT; COMBINATION; EMULSION; POSS; ROP;
D O I
10.1016/j.jcis.2011.05.062
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the research work, "click" chemistry was used to modify waterborne polyurethane (WPU) with silane coupling agent (SiCA) functionalized nano-silica. The modified WPU (CWPU) was characterized by FTIR, scanning electron microscope (SEM), thermogravimetric analysis (TGA) and contact angle measurement. The experiment results show that the modification can improve the thermal stability, hardness, and water or weather resistance of CWPU. (C) 2011 Elsevier Inc. All rights reserved.
引用
收藏
页码:483 / 490
页数:8
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