Synthesis of (S) 2-ethyl-2-methylpentanoic acid from the formate ester of (S) ethyl 2-formyl-3-hydroxy-2-methylpropionate

被引:4
|
作者
Fronza, G [1 ]
Fogliato, G [1 ]
Fuganti, C [1 ]
Grasselli, P [1 ]
Rigoni, R [1 ]
机构
[1] POLITECN MILAN,DIPARTIMENTO CHIM,CNR,CTR CHIM SOSTANZE ORGAN NAT,I-20131 MILAN,ITALY
关键词
D O I
10.1016/0040-4020(96)00880-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of (S) 2-ethyl-2-methylpentanoic acid 13 from the C-5 aldehydo ester 1, obtained through a baker's yeast transformation via C-2 and C-1 chain elongations by means of olefin-forming reactions is reported. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:14281 / 14286
页数:6
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