Preparation of novel aminated chitosan schiff's base derivative for the removal of methyl orange dye from aqueous environment and its biological applications

被引：60
|
作者：
Yuvaraja, Gutha [1 ,2 ]
Chen, Di-Yun [1 ,2 ]
Pathak, Janak L. [3 ]
Long, Jianyou [1 ,2 ]
Subbaiah, Munagapati Venkata [4 ]
Wen, Jet-Chau [4 ,5 ]
Pan, Chih-Long [6 ]
机构：
[1] Guangzhou Univ, Sch Environm Sci & Engn, Guangdong Prov Key Lab Radionuclides Pollut Contr, Guangzhou 510006, Peoples R China
[2] Guangzhou Univ, Sch Civil Engn, Guangzhou 510006, Peoples R China
[3] Guangzhou Med Univ, Affiliated Stomatol Hosp, Guangzhou Inst Oral Dis, Key Lab Oral Med, Guangzhou 510140, Peoples R China
[4] Natl Yunlin Univ Sci & Technol, Res Ctr Soil & Water Resources & Nat Disaster Pre, 123,Sect 3,Univ Rd, Touliu 640, Yunlin, Taiwan
[5] Natl Yunlin Univ Sci & Technol, Dept & Grad Sch Safety & Environm Engn, 123,Sect 3,Univ Rd, Touliu 640, Yunlin, Taiwan
[6] Natl Yunlin Univ Sci & Technol, Coll Future, Bachelor Program Interdisciplinary Studies, 123,Sect 3,Univ Rd, Touliu 640, Yunlin, Taiwan
来源：
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES | 2020年 / 146卷
关键词：
Methyl orange; Removal; Kinetics; Isotherms; Thermodynamics; GRAPHENE OXIDE; ADSORPTION-KINETICS; ENHANCED ADSORPTION; EFFECTIVE ADSORBENT; MAGNETIC COMPOSITE; CATIONIC DYES; ISOTHERMS; ACID; EQUILIBRIUM; MAGSORBENT;
D O I：
10.1016/j.ijbiomac.2019.09.236
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A novel, eco-friendly aminated chitosan Schiff's base (ACSSB@ZnO) was developed and utilized to remove MO from aqueous environment. The impact of different significant parameters, for example, pH (3-11), adsorbent dose (0.1-0.6 g), contact time (0-120 min), and temperature (303-323 K) have been explored by batch process. Kinetic data was illustrated by pseudo-second-order model and the isotherms fitted well with Langmuir isotherm model. The highest sorption capacity of ACSSB@ZnO was observed to be 111.11 mg/g at 323 K. Positive enthalpy and entropy values demonstrated that the MO adsorption procedure was an endothermic. Negative Gibbs free energy values implied the spontaneous nature of the adsorption system. Moreover, reusability experiments were studied and it can be regenerated by using NaOH as effluent. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码：1100 / 1110
页数：11
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