Steady-state heat and matter transfer at a non-uniform phase boundary

被引:1
|
作者
Phillips, LF
机构
[1] Chemistry Department, University of Canterbury, Christchurch
关键词
D O I
10.1016/0009-2614(96)00026-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fluxes of heat and matter are calculated by applying Onsager's irreversible thermodynamics to a macroscopic system which comprises a number of layers with differing transfer coefficients for heat and matter. It is shown that Eq. (1), which was previously derived for transport through a single uniform layer, applies to the composite system when suitably averaged values of transfer coefficients are used. The results are applied to calculations of the rate of CO2 transfer at a model air-sea interface which specifically includes the transition zone over which the medium changes from gas to liquid.
引用
收藏
页码:349 / 354
页数:6
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