Synthesis of photopolymers with pendant cyclic carbonate and cinnamic ester groups

被引：3
|
作者：
Park, HY [1 ]
Lee, DW [1 ]
Lee, HS [1 ]
Lim, DO [1 ]
Park, DW [1 ]
机构：
[1] Pusan Natl Univ, RIIT, Dept Chem Engn, Pusan 609735, South Korea
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2003年 / 79卷 / 02期
关键词：
photopolymer; cinnamic chloride; cyclic carbonate; quaternary ammonium salts;
D O I：
10.1023/A:1024577900530
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Photopolymers with both pendant cyclic carbonate groups and cinnamic ester groups were synthesized by the addition reaction of poly(glycidyl methacrylate-co-styrene)[poly(GMA-co-AN)] with carbon dioxide and then with cinnamoyl chloride. Soluble quaternary ammonium salt catalysts showed good yield of cinnamoyl chloride addition to the glycidyl methacrylate groups. Quaternary salt catalysts of longer alkyl chain length and of more nucleophilic anion offered higher yield of cinnamoyl chloride addition. Photochemical reaction test showed that poly(CNMA-co-DOMA-co-St) had a good photosensitivity.
引用
收藏
页码：245 / 255
页数：11
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