Synthesis and structure of (4,4'-H2bpy)[V2(HPO4)4(4,4'-bpy)2], a novel two-dimensional network compound

被引：52
|
作者：
Huang, CH
Huang, LS
Lii, KH [1 ]
机构：
[1] Natl Cent Univ, Dept Chem, Chungli 320, Taiwan
[2] Acad Sinica, Inst Chem, Taipei 115, Taiwan
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 11期
关键词：
D O I：
10.1021/ic001169g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterization of the first metal phosphate containing 4,4'-bipyridine in two distinct forms is described; the structure consists of phosphate-bridged vanadium(m) chains, which are linked through 4,4'-bipyridine ligands to form anionic ([V-2(HPO4)(4)- (4,4'-bpy)(2)](2-))(infinity) sheets with the charge-compensating uncoordinated (4,4'-H(2)bpy)(2+) cations between the sheets.
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页码：2625 / +
页数：4
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